In order to improve hydrogen production and reduce tar generation during the biomass gasification, a catalyst loaded Fe-Ce using calcined olivine as the support (Fe-Ce/olivine catalysts) was prepared through deposition-precipitation method. The characteristics of catalysts were determined by XRF, BET, XRD, and FTIR. Syngas yield, hydrogen yield, and tar yield were used to evaluate the catalyst activity. Meanwhile, the stability of catalysts was also studied. The results showed that the specific surface area and pore volume of olivine after calcined at high temperature were improved which was beneficial for the load of metals. alpha-Fe2O3 and CeO2 were the main active component of Fe-Ce/olivine catalyst. The Fe-Ce/olivine catalyst displayed a good performance on the catalytic gasification of pine sawdust with a syngas yield of 0.93 Nm(3)/kg, H-2 yield of 21.37 mol/kg, and carbon conversion rate of 55.14% at a catalytic temperature and gasification temperature of 800 degrees C. Meanwhile, the Fe-Ce/olivine catalyst could maintain a good stability after 150 minutes used.