화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.121, No.1, 199-207, 1999
Motion of CO molecules in solid C-60 probed by solid-state NMR
Polycrystalline C-60 has been intercalated with 99 atom % C-13-enriched CO gas by using high-pressure, high-temperature synthesis. The ratio of (CO)-C-13 to C-60 is determined using C-13 NMR under magic-angle spinning and is found to be almost 1:2. Static solid-state C-13 NMR spectra of (CO)-C-13-intercalated C-60 have been measured in the range between room temperature and 4 K. In the high-temperature range, i.e., between room temperature and 100 K, the CO molecules in the "octahedral" sites of the C-60 lattice reorient rapidly on the NMR time scale. At 4 K the reorientation rate of CO is so low that, on the NMR time scale, the molecule appears localized in one of the minima of the potential. Between LC and 30 K, the transition from the static to the dynamic regime can be inferred from NMR line shape changes. The temperature dependence of the line shape is modeled in terms of thermally activated jump-like reorientations of the CO molecules in the C-60 lattice. No evidence for a quantum mechanical coherent tunneling motion of the CO molecules in the octahedral sites of the C-60 lattice has been found.