화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.82, 439-447, February, 2020
DOI10.1016/j.jiec.2019.11.008  Export Citation
Polymer particles with controllable and complex structures for high immobilization of noble-metal nanoparticles
Da In Kim1, Ju Hyang Park1, Hojun Seo1, 2, Sang Gi Hong1, Hye Ji Kim1, 3, Hyungju Ahn3, Jongbok Kim4, Geon Dae Moon2, and Dong Choon Hyun1, †
  • 1Department of Polymer Science and Engineering, Kyungpook National University, Daegu 41566, South Korea
  • 2Dongnam Regional Division, Korea Institute of Industrial Technology, Busan 46938, South Korea
  • 3Pohang Accelerator Laboratory, POSTECH, Pohang, Gyeongbuk 37673, South Korea
  • 4Department of Materials Science and Engineering, Kumoh National Institute of Technology, Gumi, Gyeongbuk 39177, South Korea
E-mail:
This work demonstrates the fabrication of cationic polymer particles with controllable and complex structures for the high immobilization of noble-metal nanoparticles (NPs). The fabrication involves the use of a cationic extra monomer to synthesize polystyrene (PS) solid spheres with cationic character, followed by their transformation into complex-structured particles via the phase separation route in a seeded dispersion polymerization. Control of the phase separation enables the formation of PS particles with cage- and bowl-like shapes as well as hollow structures. The large surface areas of the complex-structured particles, as theoretically calculated using simple models, and the electrostatic attraction between them and the negatively charged noble-metal NPs, as experimentally observed, allow the high immobilization of noble-metal NPs onto their surfaces.
Keywords:Polymer particle;Complex-structured colloid;Phase separation;Noble-metal nanoparticle;Large surface area
  1. Mirkin CA, Taton TA, Nature, 405, 626 (2000)
  2. Sastry M, Lala N, Patil V, Chavan SP, Chittiboyina AG, Langmuir, 14(15), 4138 (1998)
  3. Zhou S, Zhao M, Yang TH, Xia Y, Mater. Today, 22, 108 (2019)
  4. Jiang C, Cao Y, Xiao G, Zhu R, Lu Y, RSC Adv., 7, 7531 (2017)
  5. Borodko Y, Jones L, Lee H, Frei H, Somorjai G, Langmuir, 25(12), 6665 (2009)
  6. Nallathamby PD, Lee KJ, Xu XHN, ACS Nano, 2, 1371 (2008)
  7. Deplanche K, Woods RD, Mikheenko IP, Sockett RE, Macaskie LE, Biotechnol. Bioeng., 101(5), 873 (2008)
  8. Zopes D, Stein B, Mathur S, Graf C, Langmuir, 29, 11217 (2013)
  9. Bryan WW, Jamison AC, Chinwangso P, Rittikulsittichai S, Lee TC, Lee TR, RSC Adv., 6, 68150 (2016)
  10. Huang CC, Liao HY, Shiang YC, Lin ZH, Yang Z, Chang HT, J. Mater. Chem., 19, 755 (2009)
  11. Li JF, Huang YF, Duan S, Pang R, Wu DY, Ren B, Xu X, Tian ZQ, Phys. Chem. Chem. Phys., 12, 2493 (2010)
  12. Mazumder V, Sun SH, J. Am. Chem. Soc., 131(13), 4588 (2009)
  13. Grirrane A, Corma A, Garcia H, Science, 322, 1661 (2008)
  14. Zhou J, Ren F, Wu W, Zhang SF, Xiao XH, Xu JX, Jiang CZ, J. Colloid Interface Sci., 387, 47 (2012)
  15. Gu H, Wang J, Ji Y, Wang Z, Chen W, Xue G, J. Mater. Chem. A, 1, 12471 (2013)
  16. Bleach R, Karagoz B, Prakash SM, Davis TP, Boyer C, ACS Macro Lett., 3, 591 (2014)
  17. Corma A, Garcia H, Chem. Soc. Rev., 37, 2096 (2008)
  18. Kanahara M, Shimomura M, Yabu H, Soft Matter, 10, 275 (2014)
  19. Ocwieja M, Lupa D, Adamczyk Z, Langmuir, 34(29), 8489 (2018)
  20. Kawaguchi H, Prog. Polym. Sci., 25, 1171 (2000)
  21. Gong J, Zu X, Mu W, Deng Y, Colloid Polym. Sci., 291, 239 (2013)
  22. Li JM, Ma WF, Wei C, You LJ, Guo J, Hu J, Wang CC, Langmuir, 27(23), 14539 (2011)
  23. Chang CP, Tseng CC, Ou JL, Hwu WH, Ger MD, Colloid Polym. Sci., 288, 395 (2010)
  24. Liu W, Yang XL, Xie L, J. Colloid Interface Sci., 313(2), 494 (2007)
  25. Li Y, Pan Y, Yang C, Gao Y, Wang Z, Xue G, Colloids Surf. A: Physicochem. Eng. Asp., 414, 504 (2012)
  26. Xu T, Li YZ, Zhang JX, Qi YL, Zhao X, Zhang QH, Appl. Surf. Sci., 345, 264 (2015)
  27. Lee JH, Kim DO, Song GS, Lee Y, Jung SB, Nam JD, Macromol. Rapid Commun., 28(5), 634 (2007)
  28. Kim H, Daniels ES, Dimonie VL, Klein AJ, Polym. Sci. A Polym. Chem., 46, 912 (2008)
  29. Gittins DI, Susha AS, Schoeler B, Caruso F, Adv. Mater., 14(7), 508 (2002)
  30. Ji TH, Lirtsman VG, Avny Y, Davidov D, Adv. Mater., 13(16), 1253 (2001)
  31. Okubo M, Minami H, Colloid Polym. Sci., 275, 992 (1997)
  32. Okubo M, Konishi Y, Minami H, Colloid Polym. Sci., 276, 638 (1998)
  33. Yuan CD, Mao AH, Cao JW, Xu YS, Cao TY, J. Appl. Polym. Sci., 98(4), 1505 (2005)
  34. Kida T, Mouri M, Akashi M, Angew. Chem.-Int. Edit., 45, 7534 (2006)
  35. Wang L, Liang H, Wang F, Huang LY, Liu ZP, Dong ZX, Langmuir, 29(19), 5863 (2013)
  36. Ramli RA, RSC Adv., 7, 52632 (2017)
  37. Park SH, Kim J, Hur SH, Kim DH, Kim MH, Chem. Eng. J., 348, 46 (2018)
  38. Son JH, Kim DI, Park JH, Seo H, Hong SG, Choi JH, Kim J, Moon GD, Hyun DC, Polymer, 167, 85 (2019)
  39. Luo Z, Li Y, Liu B, Chem. Commun., 53, 8649 (2017)
  40. Hoffman A, J. Am. Chem. Soc., 43, 1684 (1921)
  41. Hoffman A, J. Am. Chem. Soc., 52, 2995 (1930)
  42. Grayson M, J. Am. Chem. Soc., 85, 79 (1963)
  43. Gulka CP, Wong AC, Wright DW, Chem. Commun., 52, 1266 (2016)
  44. Hueso JL, Sebastian V, Mayoral A, Uson L, Arruebo M, Santamaria J, RSC Adv., 3, 10427 (2013)
  45. Uson L, Sebastian V, Mayoral A, Hueso JL, Eguizabal A, Arruebo M, Santamaria J, Nanoscale, 7, 10152 (2015)
  46. Vogel W, Duff DG, Baiker A, Langmuir, 11(2), 401 (1995)
  47. Westcott SL, Oldenburg SJ, Lee TR, Halas NJ, Langmuir, 14(19), 5396 (1998)
  48. Jiang ZJ, Liu CY, Sun LW, J. Phys. Chem. B, 109(5), 1730 (2005)