화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.82, 144-152, February, 2020
DOI10.1016/j.jiec.2019.10.006  Export Citation
A kirigami concept for transparent and stretchable nanofiber networks-based conductors and UV photodetectors
Juhyeon Kim1, Hyeji Park1, 2, and Soo-Hwan Jeong1, †
  • 1Department of Chemical Engineering, Kyungpook National University (KNU), 80, Daehak-Ro, Buk-Gu, Daegu 41566, Republic of Korea
  • 2Advanced Instrumentation Institute, Korea Research Institute of Standards and Science, Daejeon 34113, Republic of Korea
E-mail:
To meet the increasing demand for wearable electronics today, fabrication of the stretchable devices becomes crucial. In this respect, a stretchable conductor is an essential component for achieving stretchability of the device. Herein, a stretchable and transparent conductor unit, Au-metallized PVP (Au@PVP) nanofiber network on a kirigami-structured PDMS substrate, was newly developed. By a series of comparative studies, the effectiveness of our strategies to the invariant electrical conductivity and high stretchability is convincingly demonstrated. Our stretchable conductor showed high stretchability of 110% without significant change in resistance, ~50% increase. It also exhibited ~80% transparency, as well as excellent durability. To point out its applicability, we fabricated a transparent and stretchable photodetector having the same geometry. ZnO nanorod, the 1D transparent metal oxide nanostructure, is used as a sensing material owing to its high sensitivity for UV light and large surface to volume ratio. The resulting device showed outstanding on/off ratio of 1020 at its original state and 440 under 80% strain. Its fast response/reset time, high transparency and stable performance indicate the feasibility of the stretchable and transparent optoelectronic device.
Keywords:Stretchable;Kirigami;Transparent;Metal nanofiber network;Photodetector;Wearable electronics
  1. Cai S, Xu X, Yang W, Chen J, Fang X, Adv. Mater., 31, 180813 (2019)
  2. Rogers JA, Someya T, Huang YG, Science, 327(5973), 1603 (2010)
  3. Le VQ, Do TH, Retamal JRD, Shao PW, Lai YH, Wu WW, He JH, Chueh YL, Chu YH, Nano Energy, 56, 322 (2019)
  4. Yang Y, Liu J, Cao J, Zhou Z, Zhang X, J. Mater. Chem. C, 7, 578 (2019)
  5. Hua Q, Sun J, Liu H, Bao R, Yu R, Zhai J, Pan C, Wang ZL, Nat. Commun., 9, 244 (2018)
  6. Tang X, Ackerman MM, Shen G, Guyot-Sionnest P, Small, 15, 180492 (2019)
  7. Liu Y, Wang H, Zhao W, Zhang M, Qin H, Xie Y, Sensors, 18, 645 (2018)
  8. Xu X, Chen J, Cai S, Long Z, Zhang Y, Su L, He S, Tang C, Liu P, Peng H, Fang X, Adv. Mater., 30, 180316 (2018)
  9. Hsieh YT, Chen JT, Shih CC, Chueh CC, Chen WC, Org. Electron., 53, 339 (2018)
  10. Bade SGR, Shan X, Hoang PT, Li J, Geske T, Cai L, Pei Q, Wang C, Yu Z, Adv. Mater., 29, 160705 (2017)
  11. Kim CC, Lee HH, Oh KH, Sun JY, Science, 353(6300), 682 (2016)
  12. Huang S, Guo CF, Zhang X, Pan W, Luo X, Zhao C, Gong J, Li X, Ren ZF, Wu H, Small, 11, 5712 (2015)
  13. Kang P, Wang MC, Knapp PM, Nam S, Adv. Mater., 28(23), 4639 (2016)
  14. Pike GE, Seager CH, Phys. Rev. B, 10, 1421 (1974)
  15. Lee P, Lee J, Lee H, Yeo J, Hong S, Nam KH, Lee D, Lee SS, Ko SH, Adv. Mater., 24(25), 3326 (2012)
  16. Wu H, Kong DS, Ruan ZC, Hsu PC, Wang S, Yu ZF, Carney TJ, Hu LB, Fan SH, Cui Y, Nat. Nanotechnol., 8(6), 421 (2013)
  17. An BW, Hyun BG, Kim SY, Kim M, Lee MS, Lee K, Koo JB, Chu HY, Bae BS, Park JU, Nano Lett., 14, 6322 (2014)
  18. Zhang X, Guo W, Gao G, Que M, Pan C, Wang ZL, J. Mater. Chem. C, 4, 4733 (2016)
  19. Huang S, Liu Y, Guo CF, Ren Z, Adv. Electron. Mater., 3, 160053 (2017)
  20. Soltanian S, Rahmanian R, Gholamkhass B, Kiasari NM, Ko F, Servati P, Adv. Eng. Mater., 3, 1332 (2013)
  21. Jin Y, Hwang S, Ha H, Park H, Kang SW, Hyun S, Jeon S, Jeong SH, Adv. Electron. Mater., 2, 150030 (2016)
  22. Shyu TC, Damasceno PF, Dodd PM, Lamoureux A, Xu LZ, Shlian M, Shtein M, Glotzer SC, Kotov NA, Nat. Mater., 14(8), 785 (2015)
  23. Morikawa Y, Yamagiwa S, Sawahata H, Numano R, Koida K, Ishida M, Kawano T, IEEE Micro Electro Mechanical Systems (MEMS) 186 (2018).
  24. Wu C, Wang X, Lin L, Guo H, Wang ZL, ACS Nano, 10, 4652 (2016)
  25. Wen Z, Yang Y, Sun N, Li G, Liu Y, Chen C, Shi J, Xie L, Jiang H, Bao D, Zhuo Q, Sun X, Adv. Funct. Mater., 28, 180368 (2018)
  26. Khatib M, Huynh TP, Deng Y, Horev YD, Saliba W, Wu W, Haick H, Small, 15, 180393 (2019)
  27. Chen D, Lou Z, Jiang K, Shen G, Adv. Funct. Mater., 28, 180559 (2018)
  28. Lamoureux A, Lee K, Shlian M, Forrest SR, Shtein M, Nat. Commun., 6, 8092 (2015)
  29. Li P, Ma J, Xu H, Xue X, Liu Y, J. Mater. Chem. C, 4, 3581 (2016)
  30. Qi Z, Campbell DK, Park HS, Phys. Rev. B, 90, 245437 (2014)
  31. Zheng W, Huang W, Gao F, Yang H, Dai M, Liu G, Yang B, Zhang J, Fu YQ, Chen X, Qiu Y, Jia D, Zhou Y, Hu P, Chem. Mater., 30, 6063 (2018)
  32. Hanakata PZ, Qi Z, Campbell DK, Park HS, Nanoscale, 8, 458 (2016)
  33. Xu L, Wang X, Kim Y, Shyu TC, Lyu J, Kotov NA, ACS Nano, 10, 6156 (2016)
  34. Guo CF, Liu Q, Wang G, Wang Y, Shi Z, Suo Z, Chu CW, Ren Z, Proc. Natl. Acad. Sci. U. S. A., 112, 12332 (2015)
  35. Tang YC, Lin GJ, Han L, Qiu SG, Yang S, Yin J, Adv. Mater., 27(44), 7181 (2015)
  36. Ding S, Jiu J, Gao Y, Tian Y, Araki T, Sugahara T, Nagao S, Nogi M, Koga H, Suganuma K, Uchida H, ACS Appl. Mater. Interfaces, 8, 6190 (2016)
  37. Kim DH, Yu KC, Kim Y, Kim JW, ACS Appl. Mater. Interfaces, 7, 15214 (2015)
  38. Kim J, Park J, Jeong U, Park JW, J. Appl. Polym. Sci., 133, 43830 (2016)
  39. Jiang D, Zhang J, Lu Y, Liu K, Zhao D, Zhang Z, Shen D, Fan X, Soild State Electron., 52, 679 (2008)
  40. Look DC, Reynolds DC, Litton CW, Jones RL, Eason DB, Cantwell G, Appl. Phys. Lett., 81, 1830 (2002)
  41. Jin Y, Wang J, Sun B, Blakesley JC, Greenham NC, Nano Lett., 8, 1649 (2008)
  42. Nasiri N, Bo RH, Wang F, Fu L, Tricoli A, Adv. Mater., 27(29), 4336 (2015)
  43. Zhang ZM, Ning Y, Fang XS, J. Mater. Chem. C, 7, 223 (2019)
  44. Ning Y, Zhang ZM, Teng F, Fang XS, Small, 14, 170375 (2018)
  45. Chen MX, Zhao B, Hu GF, Fang XS, Wang H, Wang L, Luo J, Han X, Wang XD, Pan CF, Wang ZL, Adv. Funct. Mater., 28, 6 (2018)
  46. Hu K, Teng F, Zheng LX, Yu PP, Zhang ZM, Chen HY, Fang XS, Laser Photon. Rev., 11, 7 (2017)
  47. Ji LW, Peng SM, Su YK, Young SJ, Wu CZ, Cheng WB, Appl. Phys. Lett., 94, 203106 (2009)
  48. Shejale KP, Laishram D, Gupta R, Sharma RK, ChemistrySelect, 3, 7291 (2018)
  49. Kind H, Yan HQ, Messer B, Law M, Yang PD, Adv. Mater., 14(2), 158 (2002)
  50. Li QH, Gao T, Wang YG, Wang TH, Appl. Phys. Lett., 86, 123117 (2005)
  51. Soci C, Zhang A, Xiang B, Dayeh SA, Aplin DPR, Park J, Bao XY, Lo YH, Wang D, Nano Lett., 7, 1003 (2007)
  52. Hossienzadeh K, Maleki A, Daraei H, Safari M, Pawar R, Lee SM, Korean J. Chem. Eng., 36(8), 1360 (2019)
  53. Jung SH, Oh E, Lee KH, Park W, Jeong SH, Adv. Mater., 19(5), 749 (2007)
  54. Kushwaha A, Aslam M, J. Appl. Phys., 112, 054316 (2012)
  55. Yan CY, Wang JX, Wang X, Kang WB, Cui MQ, Foo CY, Lee PS, Adv. Mater., 26(6), 943 (2014)
  56. Liao XQ, Liao QL, Zhang Z, Yan XQ, Liang QJ, Wang QY, Li MH, Zhang Y, Adv. Funct. Mater., 26(18), 3074 (2016)
  57. Wang J, Yan C, Kang W, Lee PS, Nanoscale, 6, 10734 (2014)
  58. Zhou J, Gu Y, Hu Y, Mai W, Yeh PH, Bao G, Sood AK, Polla DL, Wang ZL, Appl. Phys. Lett., 94, 191103 (2009)
  59. Jie JS, Zhang WJ, Jiang Y, Meng XM, Li YQ, Lee ST, Nano Lett., 6, 1887 (2006)
  60. Kung SC, van der Veer WE, Yang F, Donavan KC, Penner RM, Nano Lett., 10, 1481 (2010)
  61. Aga RS, Jowhar D, Ueda A, Pan Z, Collins WE, Mu R, Singer KD, Shen J, Appl. Phys. Lett., 91, 232108 (2007)
  62. Heo K, Lee H, Park Y, Park J, Lim HJ, Yoon D, Lee C, Kim M, Cheong H, Park J, J. Mater. Chem., 22, 2173 (2012)