화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Materials Research, Vol.29, No.12, 741-746, December, 2019
DOI10.3740/MRSK.2019.29.12.741  Export Citation
Fabrication of Microcrystalline NaPbLa(WO4)3:Yb3+/Ho3+ Phosphors and Their Upconversion Photoluminescent Characteristics
Chang Sung Lim1, †, Victor V. Atuchin2, 3, Aleksandr S. Aleksandrovsky4, 5, Yuriy G. Denisenko6, 7, Maxim S. Molokeev8, 9, and Aleksandr S. Oreshonkov10, 11
  • 1Department of Aerospace Advanced Materials & Chemical Engineering, Hanseo University, Seosan 356-706, Republic of Korea
  • 2Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russia, Russian Federation
  • 3Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk 630090, Russia, Russian Federation
  • 4Laboratory of Coherent Optics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia, Russian Federation
  • 5Department of Photonics and Laser Technologies, Siberian Federal University, Krasnoyarsk 660041, Russia, Russian Federation
  • 6Department of Inorganic and Physical Chemistry, Tyumen State University, Tyumen 625003, Russia, Russian Federation
  • 7Department of General and Special Chemistry, Industrial University of Tyumen, Tyumen 625000, Russia, Russian Federation
  • 8Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia, Russian Federation
  • 9Siberian Federal University, Krasnoyarsk 660041, Russia, Russian Federation
  • 10Siberian Federal University, Krasnoyarsk 660041, Russia, Korea
  • 11Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia, Korea
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New triple tungstate phosphors NaPbLa(WO4)3:Yb3+/Ho3+ (x = Yb3+/Ho3+ = 7, 8, 9, 10) are successfully fabricated by microwave assisted sol-gel synthesis and their structural and frequency upconversion (UC) characteristics are investigated. The compounds crystallized in the tetragonal space group I41/a and the NaPbLa(WO4)3 host have unit cell parameters a = 5.3927(1) and c = 11.7961(3) A, V = 343.05(2) A3, Z = 4. Under excitation at 980 nm, the phosphors have yellowish green emissions, which are derived from the intense 5S2/ 5F4 → 5I8 transitions of Ho3+ ions in the green spectral range and strong 5F5 → 5I8 transitions in the red spectral range. The optimal Yb3+:Ho3+ ratio is revealed to be x = 9, which is attributed to the quenching effect of Ho3+ ions, as indicated by the composition dependence. The UC characteristics are evaluated in detail under consideration of the pump power dependence and Commission Internationale de L'Eclairage chromaticity. The spectroscopic features of Raman spectra are discussed in terms of the superposition of Ho3+ luminescence and vibrational lines. The possibility of controlling the spectral distribution of UC luminescence by the chemical content of tungstate hosts is demonstrated.
Keywords:yellowish green phosphor;triple tungstate;microwave assisted sol-gel;upconversion characteristics
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