화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.102, No.9, 5253-5261, 2019
Enhancement of energy storage density in antiferroelectric PbZrO3 films via the incorporation of gold nanoparticles
In this work, antiferroelectric Au-PbZrO3 (Au-PZO) nanocomposite thin films were prepared by chemical solution deposition (CSD), and the effects of Au concentration on the antiferroelectric properties and the recoverable energy density were investigated. The results showed that the optimal Au concentration in the Au-PZO nanocomposite thin films was about 1mol% for structural and electric properties. In the Au-PZO nanocomposite thin films with 1mol% Au, Au nanoparticles (NPs) were distributed uniformly in the perovskite PZO matrix. Moreover, the recoverable energy density was 10.8J/cm(3) at 600kV/cm, which is 42% higher than that of the pure PZO films. The results demonstrate that adding an appropriate amount of noble metal NPs in antiferroelectric thin films is an effective method to improve the energy storage properties.