Journal of Colloid and Interface Science, Vol.555, 460-469, 2019
Preparation of silver-nanoparticle-loaded magnetic biochar/poly (dopamine) composite as catalyst for reduction of organic dyes
In the present study, Ag nanoparticles loaded on polydopamine coated magnetic biochar (MC-PDA-Ag) catalyst was prepared by in-situ reduction approach. The morphology, composition, and structure of MC-PDA-Ag were characterized by the transmission electron microscopy (TEM), the scanning electron microscope (SEM), X-ray diffractometer (XRD), X-ray photoelectron spectroscopy (XPS), and vibrating sample magnetometer (VSM). Catalytic reduction tests confirmed that MC-PDA-Ag catalyst showed excellent catalytic performance on the model dyes (MB, RhB, and MO) in the presence of NaBH4. The reduction efficiency of MB exceeded 90% by MC-PDA-Ag even under different initial pH (3-11) and different NaNO3 concentrations (0-0.5 M) within 5 min, indicating that the MC-PDA-Ag catalyst has potential strong universal adaptability in dye wastewater treatment. Furthermore, no significant decrease in catalytic ability was observed after 5 recycles, and the catalyst could be separated by an external magnet, indicating that this as-prepared catalyst exhibited high reusability and easy separability. These results suggest that MC-PDA-Ag composite catalyst can be used as an efficient catalyst for the reduction of organic dyes, and shows great potential application in wastewater treatment. (C) 2019 Elsevier Inc. All rights reserved.
Keywords:Magnetic carbon;Silver nanoparticles;Catalytic performance;Catalytic stability;Water treatment