Recently, the preparation of hydroxide exchange membranes (HEMs) without ether bonds have attracted much attention because of their high chemical stability. Hence, ether-bond free, highly durable, and conductive poly(arylene piperidine)s (PAPips) tethered with heterocyclic ammonium via hexyl spacer chains were prepared successfully for HEMs via a facile synthetic procedure. The effect of the cationic groups (quaternary ammonium, piperidinium, and morpholinium) on the properties of the corresponding PAPip-based HEMs, including the morphology, hydroxide conductivity, and alkaline and chemical stability were systematically investigated. The as-designed PAPip-based membranes exhibited excellent overall performance. The membranes attached with piperidinium (IEC = 1.64 mmol g(-1)) exhibited a hydroxide conductivity of 0.082 S cm(-1) at 80 degrees C and exhibited significant alkaline stability which maintained 80.1% of its conductivity after immersion in 1 M NaOH at 80 degrees C for 1500 h. The as-prepared membrane also presented a peak power density of 76 mW cm(-2) at 80 degrees C in a H-2/O-2 HEMFC. The resulting HEMs also showed excellent mechanical properties, thermal stability, and well-defined phase separation. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.