화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.44, No.48, 26545-26553, 2019
High-performance anode for solid acid fuel cells prepared by mixing carbon substances with anode catalysts
Optimization of Pt-based electrode structure is a key to enhance power generation performance of fuel cells and to reduce the Pt loading. This paper presents a new methodology for anode fabrication for solid acid fuel cells (SAFCs) operating at ca. 200 degrees C. Our membrane electrode assembly for SAFCs consisted of a CsH2PO4/SiP2O7 composite electrolyte and Pt-based electrodes. To obtain the anode, a commercial Pt/C catalyst and carbon substance, such as carbon black and carbon nanofiber, were mixed. The composite anode with Pt loading = 0.5 mg cm(-2) demonstrated superior current-voltage characteristics to a benchmark Pt/C anode with Pt loading = 1 mg cm(-2). We consider that the mixing of Pt/C catalyst and carbon substrate facilitated H-2 mass transfer and increased the number of active sites. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.