This paper presents seasonal-energy storage of solar energy for the heating of buildings. We distinguish several types of seasonal storage, such as latent, sensible, and chemical storage, among which the thermochemical storage is used and analysed in this research. In the first part, a laboratory heat-storage tank, which was made in the laboratory for heating, sanitary, and solar technology and air conditioning from the Faculty of Mechanical Engineering, University of Ljubljana, Slovenia, was presented. The experimental model was tested for charging and discharging mode. Two types of numerical models for sorption thermal-energy storage exist, which are microscale and macroscale (integral). For microscale analysis, the analysis system (ANSYS) model can be used to simulate the behaviour in the adsorption reactor. On macroscale or integral scale, TRaNsient SYStem (TRNSYS) model was used to perform the operation of the storages on the yearly basis. In the second part the simulation of the underfloor heating system operation with a built-in storage tank was carried out for two locations, Ljubljana and Portoroz. Furthermore, the comparison between a thermochemical and sensible-heat storage was performed with TRNSYS and Excel software. In this comparison, the focus was on the surface parameters of the SCs and volume of the thermal-storage tank for the coverage of the energy demand for selected building. With this analysis, we would like to show the advantage of the thermochemical storage system, to provide greater coverage of the energy demand for the operation of the building, compared with the seasonal sensible-heat storage (SSHS). Such a heat-storage technology could, in the future, be a key contributor to the more environmentally friendly and more sustainable way of delivering energy needs for buildings.