Elimination of Chlorine (Radical) or Tosylate (Anion) from C2’ of Nucleoside C3’ Free-Radicals as Model Reactions Postulated to Occur at the Active-Site of Ribonucleotide Reductases

Robins MJ; Guo ZQ; Wnuk SF

Journal of the American Chemical Society, Vol.119, No.15, 3637-3638, 1997

Robins MJ, Guo ZQ, Wnuk SF

Keywords:ACID RELATED-COMPOUNDS;DEOXYGENATIVE (1;2)-HYDRIDE SHIFT;ESCHERICHIA-COLI;SECONDARY ALCOHOLS;DIPHOSPHATE REDUCTASE;OXIDATION;INACTIVATION;GENERATION;MECHANISM;PROTEIN