The results of structure and phase composition change in tungsten after compression plasma flow and highintensive pulsed ion beams impacts are discussed. The compression plasma flows with the absorbed energy in range 35-70 J/cm(2) were used for the sub-surface modification. The preliminary Ti coating deposition on the tungsten surface allowed us to form W-Ti alloys by plasma flows treatment. The layer of the W-Ti alloy consists of solid solutions W(Ti) and beta-Ti(W) as well as nitride phase (Ti, W) N. The high-intensive pulsed ion beam impact provides the tungsten carbide W2C formation in the sub-surface layer. When forming the W-Ti alloy the carbon ions implanted into the tungsten take part in the carbo-nitride (Ti, W)(N, C) formation without brittle W2C phase.