The present study reports the microstructural and morphological changes during high energy ball milling of Cu with Ag and Graphite flakes. XRD patterns of ball milled Cu-Ag showed a reduction in the intensity of Ag peaks (1 1 1) and an increase in the lattice parameter of Cu. With an increase in milling time, the formation of metastable Cu-Ag solid solution was observed. Lattice parameter values for 40 h milled Cu (3.6169 angstrom) and Cu-GF composites (3.6166 angstrom) indicated that C does not dissolve in Cu. The lattice parameter of Cu in milled Cu-Ag-graphite flake was lower compared to milled Cu-Ag mixture indicating that graphite flakes inhibit solid solution formation. Raman spectra revealed that graphite flakes were converted into multilayer graphene after 10 h of milling. The crystallite size of Cu in the milled powders decreased with increase in milling time and reached a value of similar to 25 nm after 35 h of milling. The lattice strain also increased with milling time. The D-10, D-50 and D-90 size reduced appreciably after 5 h of milling. (C) 2019 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.