화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.80, 345-351, December, 2019
DOI10.1016/j.jiec.2019.08.013  Export Citation
Cost-effective and eco-friendly synthesis of MIL-101(Cr) from waste hexavalent chromium and its application for carbon monoxide separation
The Ky Vo1, 2, Jeong-Hoon Kim3, Hyuk Taek Kwon4, †, and Jinsoo Kim1, †
  • 1Department of Chemical Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin, Gyeonggi-do 17104, Republic of Korea
  • 2Department of Chemical Engineering, Industrial University of Ho Chi Minh City, 12 Nguyen Van Bao, Go Vap, Ho Chi Minh City, Viet Nam, Korea
  • 3Greenhouse Gas Separation and Recovery Research Group, Carbon Resources Institute, Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 34132, Republic of Korea
  • 4Department of Chemical Engineering, Pukyong National University, 45 Yongso-ro, Nam-gu, Busan 48513, Republic of Korea
E-mail:,
Conventionally, MIL-101(Cr) has been directly prepared from analytically pure trivalent chromium (Cr(III)) with the assistance of hydrofluoric acid (HF). Here, we report a novel approach of HF-free synthesis of MIL-101(Cr) using a waste Cr source. A wastewater model containing a high concentration of hexavalent Cr (Cr(VI)) was first reduced by sulfite to obtain Cr(III) at room temperature and subsequently, the resulting solution was directly used as a precursor for MIL-101(Cr) synthesis without HF. The synthesized MIL-101(Cr) had surface area of 2850 m2/g and pore volume of 1.54 cm3/g which are comparable to the one conventionally prepared with analytically pure Cr(III). The MIL-101(Cr) after Cu(I) loading became CO-selective π complexation adsorbents, showing much higher CO adsorption capacity (2.82 mmol/g) than CO2 (0.85 mmol/g) and N2 (0.08 mmol/g).
Keywords:Metal-organic frameworks;MIL-101(Cr);HF-free synthesis;Chromium waste recycle;π complexation adsorbent;CO capture
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