화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.80, 205-216, December, 2019
DOI10.1016/j.jiec.2019.07.050  Export Citation
Keggin-type polyoxometalates supported on PANI-coated CuS: Synthesis, characterization and application as the efficient adsorbents for selective dye removal
Firouzeh Siadatnasab1, Kazem Karami1, †, and Alireza Khataee2, 3, †
  • 1Department of Chemistry, Isfahan University of Technology, Isfahan, 84156/83111, Iran
  • 2Nanomaterials based Water Treatment Research Group, Ton Duc Thang University, Ho Chi Minh City, Vietnam
  • 3Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City, Vietnam
E-mail:,
In this work, Keggin type polyoxometalates H3PW12O40 (PW12), H3PMo12O40 (PMo12) and H4SiW12O40 (SiW12), were supported on polyaniline (PANI)-coated CuS nanoparticles by a facile stepwise modification method. These novel nanohybrids 1-3 (denoted as CuS@PANI/PW12 (1), CuS@PANI/PMo12 (2), and CuS@PANI/SiW12 (3)) were fully characterized. The adsorption efficiency of these novel nanohybrids were evaluated for removing methylene blue (MB) and methyl orange (MO) that exhibited high selectivity and high adsorption rate for cationic MB rather than anionic MO. The adsorption results demonstrated a good ability to remove 25 mg L-1 MB with the removal rates of ≥93%. The efficiency of nanohybrid 1 for the removal of MB was evaluated by several factors, such as pH, adsorbent dose, initial dye concentration and temperature. The adsorption isotherms and adsorption kinetic can be well described by the Langmuir isotherm model and the pseudo second order kinetic for MB, respectively. Moreover, the maximum adsorption capacity of MB reached 83.3 mg g-1 in the study of the Langmuir adsorption isotherm, respectively. Thermodynamic studies show that the MB adsorption is a spontaneous endothermic process. The nanohybrids can be easily separated and reused without any change in performances and structures.
Keywords:CuS@PANI;Keggin-type polyoxometalates;Nanohybrids;Adsorption;Dye removal
  1. Farhadi S, Siadatnasab F, Chin. J. Catal., 37, 1487 (2016)
  2. Hoseini AA, Farhadi S, Zabardasti A, Appl. Organomet. Chem., e4656 (2018).
  3. Farhadi S, Siadatnasab F, Desalin. Water. Treat., 66, 299 (2017)
  4. Nguyen CH, Juang RS, J. Ind. Eng. Chem. (2019).
  5. Farhadi S, Dusek M, Siadatnasab F, Eigner V, Polyhedron, 126, 227 (2017)
  6. Farhadi S, Siadatnasab F, Mater. Res. Bull., 83, 345 (2016)
  7. Ferrer-Polonio E, Perez-Uz B, Mendoza-Roca JA, Iborra-Clar A, Pastor-Alcaniz L, J. Ind. Eng. Chem., 56, 364 (2017)
  8. Wang U, Zhu L, Wang X, Zheng W, Hao C, Jiang C, Wu J, J. Ind. Eng. Chem., 61, 321 (2018)
  9. Yoo SH, Lee SI, Joh HI, Lee SH, J. Ind. Eng. Chem., 63, 27 (2018)
  10. Yin W, Hao S, Cao H, RSC Adv., 7, 4062 (2017)
  11. Sewu DD, Boakye P, Jung H, Woo SH, Bioresour. Technol., 244, 1142 (2017)
  12. Park JH, Hwang RH, Yoon HC, Yi KB, J. Ind. Eng. Chem. (2019).
  13. Lim JM, Park JH, Park JT, Bae SJ, J. Ind. Eng. Chem., 71, 378 (2019)
  14. Liu CG, Zheng T, Liu S, Zhang HY, J. Mol. Struct., 1110, 44 (2016)
  15. Zhan C, Zhong M, Chen F, Yang J, Cao X, Jiang X, Desalin. Water. Treat., 53, 2970 (2015)
  16. Sivakumar R, Thomas J, Yoon M, J. Photochem, Photobiol. C, Photochem. Rev., 13, 277 (2012)
  17. Marci G, Garcia-Lopez E, Bellardita M, Parisi F, Colbeau-Justin C, Sorgues S, Liotta L, Palmisano L, Phys. Chem. Chem. Phys., 15, 13329 (2013)
  18. Qu XS, Guo YH, Hu CW, J. Mol. Catal. A-Chem., 262(1-2), 128 (2007)
  19. Ahmed I, Wang XX, Boualili N, Xu HL, Farha R, Goldmann M, Ruhlmann L, Appl. Catal. A: Gen., 447, 89 (2012)
  20. He JJ, Sun HQ, Indrawirawan S, Duan XG, Tade MO, Wang SB, J. Colloid Interface Sci., 456, 15 (2015)
  21. Li PH, Li BL, An ZM, Mo LP, Cui ZS, Zhang ZH, Adv. Synth. Catal., 355, 2952 (2013)
  22. Siadatnasab F, Farhadi S, Khataee A, Ultrason. Sonochem., 44, 359 (2018)
  23. Theerthagiri J, Senthil R, Malathi A, Selvi A, Madhavan J, Ashokkumar M, RSC Adv., 5, 52718 (2015)
  24. Liu P, Huang Y, Yan J, Yang Y, Zhao Y, ACS Appl. Mater. Interfaces, 8, 5536 (2016)
  25. Shanan ZJ, IOSR Int. J. Res. Meth. Educ., 5, 2320 (2015)
  26. Zhang Y, Wang D, Wang Q, Zheng W, Mater. Des., 160, 870 (2018)
  27. Kooti M, Kharazi P, Motamedi H, J. Mater. Sci. Technol., 30, 656 (2014)
  28. Hu J, Jia FF, Song YF, Chem. Eng. J., 326, 273 (2017)
  29. Papagianni GG, Stergiou DV, Armatas GS, Kanatzidis MG, Prodromidis MI, Sens. Actuators B-Chem., 173, 346 (2012)
  30. Khan JA, Qasim M, Singh BR, Singh S, Shoeb M, Khan W, Das D, Naqvi AH, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 109, 313 (2013)
  31. Rafiee E, Khodayari M, J. Mol. Catal. A-Chem., 398, 336 (2015)
  32. Nemade K, Waghuley S, LPG sensing application of graphene/CeO2 quantum dots composite, AIP, pp.1258-1259 2013.
  33. Wang SX, Tan ZC, Li YS, Sun LX, Zhang T, Thermochim. Acta, 441(2), 191 (2006)
  34. Rafiee E, Eavani S, J. Mol. Catal. A-Chem., 373, 30 (2013)
  35. Rafiee E, Eavani S, Rashidzadeh S, Joshaghani M, Inorg. Chim. Acta., 362, 3555 (2009)
  36. Wang CC, Li JR, Lv XL, Zhang YQ, Guo G, Energy. Environ. Sci., 7, 2831 (2014)
  37. Hasan M, Ansari MO, Cho MH, Lee M, J. Ind. Eng. Chem., 22, 147 (2015)
  38. Pope VMT, Heteropoly and Isopoly Oxometalates, Springer-Verlag, Berlin, 1983.
  39. Salavati H, Tavakkoli N, Hosseinpoor M, Ultrason. Sonochem., 19, 546 (2012)
  40. Silva JB, De Brito W, Mohallem ND, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 112, 182 (2004)
  41. Farhadi S, Siadatnasab F, Khataee A, Ultrason. Sonochem., 37, 298 (2017)
  42. Almeida LCP, Goncalves AD, Benedetti JE, Miranda PCML, Passoni LC, Nogueira AF, J. Mater. Sci., 45(18), 5054 (2010)
  43. Pourzare K, Farhadi S, Mansourpanah Y, Appl. Organomet. Chem., 32, e4341 (2018)
  44. Liu XX, Gong WP, Luo J, Zou CT, Yang Y, Yang SJ, Appl. Surf. Sci., 362, 517 (2016)
  45. Zou C, Zhang Z, Xu X, Gong Q, Li J, Wu CD, J. Am. Chem. Soc., 134, 87 (2011)
  46. Farhadi S, Amini MM, Dusek M, Kucerakova M, Mahmoudi F, J. Mol. Struct., 1130, 59+2 (2017)
  47. Mahmoudi F, Farhadi S, Machek P, Jarosova M, Polyhedron, 158, 423 (2019)
  48. Ayad MM, El-Nasr AA, J. Phys. Chem. C., 114, 14377 (2010)
  49. Agarwal S, Tyagi I, Gupta VK, Golbaz F, Golikand AN, Moradi O, J. Mol. Liq., 218, 494 (2016)
  50. Mu B, Tang J, Zhang L, Wang A, Appl. Clay. Sci., 132, 7 (2016)
  51. Pandimurugan R, Thambidurai S, J. Environ. Chem. Eng., 4, 1332 (2016)
  52. Gupta VK, Pathania D, Kothiyal N, Sharma G, J. Mol. Liq., 190, 139 (2014)
  53. Ayad MM, El-Nasr AA, Stejskal J, J. Ind. Eng. Chem., 18(6), 1964 (2012)
  54. Ayad M, Zaghlol S, Chem. Eng. J., 204, 79 (2012)
  55. Yao YJ, Xu FF, Chen M, Xu ZX, Zhu ZW, Bioresour. Technol., 101(9), 3040 (2010)
  56. Wang S, Boyjoo Y, Choueib A, Chemosphere, 60, 1401 (2005)
  57. Liu T, Li Y, Du Q, Sun J, Jiao Y, Yang G, Wang Z, Xia Y, Zhang W, Wang K, Colloids Surf. B: Biointerfaces, 90, 197 (2012)
  58. Zhou Q, Gao Q, Luo W, Yan C, Ji Z, Duan P, Colloids Surf. A: Physicochem. Eng. Asp., 470, 248 (2015)
  59. Minitha CR, Lalitha M, Jeyachandran YL, Senthilkumar L, Kumar RTR, Mater. Chem. Phys., 194, 243 (2017)
  60. Rao VVB, Rao SRM, Chem. Eng. J., 116(1), 77 (2006)
  61. Fu JW, Chen ZH, Wang MH, Liu SJ, Zhang JH, Zhang JN, Han RP, Xu Q, Chem. Eng. J., 259, 53 (2015)