Preparation of magnetic activated carbon-chitosan nanocomposite for crystal violet adsorption

Ferda Civan Cavusoglu; Seher Akan; Ezgi Aleyna Arı; Ezgi Cetinkaya; Elif Colak; Gamze Nur Dastan; Semina Deniz; Damla Erdem; Melda Koksal; Sevgi Korkmaz; Nursena Onsekiz; Betul Orucoglu; Didem Ozkaya; Hamdi Bugra Uslu; Caglanur Unal; Ogulcan Yildiz; Seyma Ozkara-Aydinoglu; Sahika Sena Bayazit

Korean Journal of Chemical Engineering, Vol.36, No.11, 1915-1921, November, 2019

DOI10.1007/s11814-019-0377-9 Export Citation

Preparation of magnetic activated carbon-chitosan nanocomposite for crystal violet adsorption

Ferda Civan Cavusoglu, Seher Akan, Ezgi Aleyna Arı, Ezgi Cetinkaya, Elif Colak, Gamze Nur Dastan, Semina Deniz, Damla Erdem, Melda Koksal, Sevgi Korkmaz, Nursena Onsekiz, Betul Orucoglu, Didem Ozkaya, Hamdi Bugra Uslu, Caglanur Unal, Ogulcan Yildiz, Seyma Ozkara-Aydinoglu, and Sahika Sena Bayazit^†

Engineering & Architecture Faculty, Chemical Engineering Department, Beykent University, 34396 Istanbul, Turkey

E-mail:

Magnetic, cheap and versatile adsorbents were developed for crystal violet (CV) adsorption in this study. These adsorbents are magnetic activated carbon (AC-Fe3O4) and chitosan grafted magnetic activated carbon (Chitosan- AC-Fe3O4). Fe3O4 and chitosan were also used for adsorption. X-ray diffraction (XRD), scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), zeta potential analysis and Fourier transform infrared spectroscopy (FTIR) methods were used for characterization of adsorbents. Adsorption parameters for CV were investigated. Raw chitosan and Fe3O4 were also used for CV adsorption to compare the results of composites. The chosen adsorption parameters are amount of adsorbent, contact time, initial CV concentration, and temperature. The equilibrium period was observed to be very short for chitosan and Fe3O4 nanoparticles. The adsorption efficiencies of these adsorbents are very low. AC-Fe3O4 and AC-Fe3O4-Chitosan nanoparticles reached equilibrium at 80min. The all adsorbent-CV systems followed pseudo second-order kinetic model. AC-Fe3O4 and AC-Fe3O4-Chitosan composites suited non-linear Freundlich isotherm for all temperatures (298, 308 and 318 K). Regeneration of adsorbents was also investigated. 1M of acetic acid and 0.1M of NaOH solutions were tested. Acetic acid solution desorbed CV better than NaOH solution at 6 hours.

Keywords:Crystal Violet;Adsorption;Activated Carbon;Magnetite;Chitosan

[References]

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[Referenced By]

[1] Rai P, Gautam RK, Banerjee S, Rawat V, Chattopadhyaya MCC, J. Environ. Chem. Eng., 3(4), 2281 (2015)

[2] Kumari HJ, Krishnamoorthy P, Arumugam TKK, Radhakrishnan S, Vasudevan D, Int. J. Biol. Macromol., 96, 324 (2017)

[3] Xu B, Zheng H, Wang Y, An Y, Luo K, Zhao C, Xiang W, Int. J. Biol. Macromol., 112, 648 (2018)

[4] Sellaoui L, Dotto GL, Peres EC, Benguerba Y, Lima EC, Lamine AB, Erto A, J. Mol. Liq., 248, 890 (2017)

[5] Ma H, Pu SY, Hou YQ, Zhu RX, Zinchenko A, Chu W, Chem. Eng. J., 345, 556 (2018)

[6] Huo Y, Wu H, Wang Z, Wang F, Liu Y, Feng Y, Zhao Y, Colloids Surf. A: Physicochem. Eng. Asp., 549, 174 (2018)

[7] Fabryanty R, Valencia C, Soetaredjo FE, Putro JN, Santoso SP, Kurniawan A, Ju YHH, Ismadji S, J. Environ. Chem. Eng., 5(6), 5677 (2017)

[8] Othman NH, Alias NH, Shahruddin MZ, Abu Bakar NF, Him NRN, Lau WJ, J. Environ. Chem. Eng., 6(2), 2803 (2018)

[9] de Souza TNV, de Carvalho SML, Vieira MGA, da Silva MGC, Brasil DDB, Appl. Surf. Sci., 448, 662 (2018)

[10] Subramani SE, Thinakaran N, Process Saf. Environ. Protect., 106, 1 (2017)

[11] Monash P, Pugazhenthi G, Adsorption, 15(4), 390 (2009)

[12] Li G, Li H, Mi X, Zhao W, Korean J. Chem. Eng., 36(8), 1274 (2019)

[13] Kazeem TS, Zubair M, Daud M, Mu’azu ND, Al-Harthi MA, Korean J. Chem. Eng., 36(7), 1057 (2019)

[14] Hossienzadeh K, Maleki A, Daraei H, Safari M, Pawar R, Lee SM, Korean J. Chem. Eng., 36(8), 1360 (2019)

[15] Qu S, Wang J, Kong J, Yang P, Chen G, Talanta, 71(3), 1096 (2007)

[16] Danalioglu ST, Bayazit SS, Kerkez Kuyumcu O, Salam MA, J. Mol. Liq., 240, 589 (2017)

[17] Bordbar AK, Rastegari AA, Amiri R, Ranjbakhsh E, Abbasi M, Khosropour AR, Biotechnol. Res. Int., 2014, 705068 (2014)

[18] Hu P, Kang L , Chang T, Yang F, Wang H, Zhang Y, Yang J, Wang K, Du J, Yang Z, J. Alloy. Compd., 728, 88 (2017)

[19] Darwish MSA, Stibor I, J. Dispersion Sci. Technol., 37, 1793 (2016)

[20] Lagergren S, Sven K, Vetenskademiens Handl., 24, 1 (1898)

[21] Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)

[22] Wan J, Tao T, Zhang Y, Liang X, Zhou A, Zhu C, Choi JW, Luo S, RSC Adv., 6(28), 23233 (2016)

[23] Inyang HI, Onwawoma A, Bae S, Soil Tillage Res., 155, 124 (2016)

[24] Largitte L, Pasquier R, Chem. Eng. Res. Des., 109, 495 (2016)

[25] Langmuir I, J. Am. Chem. Soc., 40(9), 1361 (1918)

[26] Freundlich H, Zeitschrift F{u}r Phys. Chemie, 57, 385 (1906)

[27] Wei H, Han L, Tang Y, Ren J, Zhao Z, Jia L, J. Mater. Chem. B, 3(8), 1646 (2015)

[28] Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2 (2010)

[29] Chakraborty S, Chowdhury S, Das Saha P, Carbohydr. Polym., 86(4), 1533 (2011)

[30] Tahir N, Bhatti HN, Iqbal M, Noreen S, Int. J. Biol. Macromol., 94, 210 (2017)