화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.27, No.10, 931-937, October, 2019
DOI10.1007/s13233-019-7133-1  Export Citation
Triphenylphosphine-Containing Thermo-Responsive Copolymers: Synthesis, Characterization and Catalysis Application
Tao Chen1, 2, †, Shuo Zhang2, Laiyu Hua2, Zhenkai Xu2, Lei Zhou2, and Jiping Wang1, 3, †
  • 1Key Laboratory of Advanced Textile Materials & Manufacturing Technology, Ministry of Education; Eco-Dyeing and Finishing Engineering Research Center, Ministry of Education; National Base for International Science and Technology Cooperation in Textiles and, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, P. R. China
  • 2Silk Institute, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, P. R. China
  • 3Fashion College of Technology, Shanghai University of Engineering Science, Shanghai 201620, P. R. China
E-mail:,
Triphenylphosphine-containing thermo-responsive copolymers of 4-(diphenylphosphino) styrene (DPPS), di(ethylene glycol) methyl ether methacrylate (DEGMA) and oligo(ethylene glycol) methyl ether methacrylate (average molecule weight is 300, OEGMA300) were synthesized by free-radical copolymerization using azodiisobutyronitrile (AIBN) as an initiator in solution polymerization. A series of copolymers P(DEGMA-co-DPPS-co-OEGMA300) with different lower critical solution temperature (LCST) were synthesized. The synthesized copolymers were well characterized by 1H NMR, 31P NMR and gel permeation chromatography (GPC). Based on the copolymers, a thermo-responsive and water soluble assembled catalyst of palladium acetate was developed. In the presence of the thermo-responsive copolymer-supported palladium catalyst, the Suzuki-Miyaura reaction proceeded efficiently in water. The catalyst was reused at least five cycles without obvious decrease in catalytic activity and can be easily recovered by heating/centrifugation of the polymer aqueous solution.
Keywords:thermo-responsive copolymers;triphenylphosphine;polymer-supported palladium catalyst;Suzuki-Miyaura reaction
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