Silica-coated magnetite nanoparticles functionalized with betaine and their use as an adsorbent for Mo(VI) and Re(VII) species from acidic aqueous solutions

Ian Alfaro; Lorena Molina; Pablo González; José Gaete; Fernando Valenzuela; José F. Marco; César Sáez; Carlos Basualto

Journal of Industrial and Engineering Chemistry, Vol.78, 271-283, October, 2019

DOI10.1016/j.jiec.2019.06.002 Export Citation

Silica-coated magnetite nanoparticles functionalized with betaine and their use as an adsorbent for Mo(VI) and Re(VII) species from acidic aqueous solutions

Ian Alfaro¹, Lorena Molina¹, Pablo González¹, José Gaete¹, Fernando Valenzuela¹, José F. Marco², César Sáez^{3, 4}, and Carlos Basualto^{1, †}

¹Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Santos Dumont 964, Independencia, Santiago, Chile
²Instituto de Química-Física Rocasolano, CSIC, Calle Serrano 119, Madrid E-28006, Spain Instituto de España, Spain
³Departamento de Ingeniería Química y Bioprocesos, Pontificia Universidad Católica de Chile, Av. Vicuña Mackenna 4860, Santiago, Chile
⁴Centro de Investigación en Nanotecnología y Materiales Avanzados CIEN-UC, Pontificia Universidad Católica de Chile, Av. Vicuña Mackenna 4860, Santiago, Chile

E-mail:

The aim of this work is to produce a superparamagnetic core-shell adsorbent material composed of magnetite nanoparticles coated with a silica layer and functionalized with betaine for applications associated with the recovery of molybdenum and rhenium anions from highly acidic aqueous solutions. The resulting nanoparticles with a quaternary amine surface were predominantly spherical with average diameters of 14.3 ± 1.7 nm. Adsorption experiments at pH values of 1-2 confirmed that it was possible to uptake molybdate and perrhenate species using this adsorbent nanomaterial, achieving maximum loading capacities of 15 mg/gMNP for Mo and 19 mg/gMNP for Re.

Keywords:Betaine-functionalized magnetite;nanoparticles;Core-shell adsorbent for Mo and Re

[References]

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Sellaoui L, Soetaredjo FE, Ismadji S, Bonilla-Petriciolet A, Belver C, Bedia J, Ben Lamine A, Erto A, Chem. Eng. J., 354, 569 (2018)
Ma J, Qin G, Zhang Y, Sun J, Wang S, Jiang L, J. Clean Prod., 182, 776 (2018)
Lu F, Astruc D, Coord. Chem. Rev., 356, 147 (2018)
Li J, Chen M, Gao Z, Du J, Yang W, Yin M, Colloids Surf. B: Biointerfaces, 146, 468 (2016)
Rumenapp C, Gleich B, Mannherz HG, Haase A, J. Magn. Magn. Mater., 380, 271 (2015)
de Vries JW, Schnichels S, Hurst J, Strudel L, Gruszka A, Kwak M, Bartz-Schmidt KU, Spitzer MS, Herrmann A, Biomaterials, 157, 98 (2018)
Kroger APP, Paulusse JMJ, J. Control. Release, 286, 326 (2018)
Yousefi T, Khanchi AR, Ahmadi SJ, Rofouei MK, Yavari R, Davarkhah R, Myanji B, J. Hazard. Mater., 215-216, 266 (2012)
Chowdhury SR, Yanful EK, Pratt AR, J. Hazard. Mater., 235-236, 246 (2012)
Jiang WJ, Pelaez M, Dionysiou DD, Entezari MH, Tsoutsou D, O'Shea K, Chem. Eng. J., 222, 527 (2013)
Cendrowski K, Sikora P, Zielinska B, Horszczaruk E, Mijowska E, Appl. Surf. Sci., 407, 391 (2017)
Yazdani F, Fattahi B, Azizi N, J. Magn. Magn. Mater., 406, 207 (2016)
Aljarrah MT, Al-Harahsheh MS, Mayyas M, Alrebaki M, J. Environ. Chem. Eng., 6(5), 5662 (2018)
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Roca AG, Marco JF, Morales MP, Serna CJ, J. Phys. Chem. C, 111(13), 18577 (2007)
Arevalo P, Isasi J, Caballero AC, Marco JF, Martin-Hernandez F, Ceram. Int., 43(13), 10333 (2017)
Grosvenor AP, Kobe BA, Biesinger MC, McIntyre NC, Surf. Interface Anal., 36(12), 1564 (2004)
Yamashita T, Hayes P, Appl. Surf. Sci., 254(8), 2441 (2008)
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Alfonsetti R, De Simone G, Lozzi L, Passacantando M, Picozzi P, SiO SS, Surf. Interface Anal., 22, 89 (1994)
Li K, Zeng Z, Xiong J, Yan L, Guo H, Liu S, Dai Y, Chen T, Colloids Surf. A: Physicochem. Eng. Asp., 465, 113 (2015)
Cao W, Wang ZQ, Zeng QL, Shen CH, Appl. Surf. Sci., 389, 404 (2016)
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Abbas M, Rao BP, Islam MN, Naga SM, Takahashi M, Kim C, Ceram. Int., 40(1), 1379 (2014)
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Thurm S, Odenbach S, Phys. Fluids, 15(6), 1658 (2003)
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Ho YS, McKay G, Process Saf. Environ. Protect., 76(4), 332 (1998)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Sen Gupta S, Bhattacharyya KG, Adv. Colloid Interface Sci., 162, 39 (2011)
Wu FC, Tseng RL, Juang RS, Chem. Eng. J., 150(2-3), 366 (2009)
Dickson JO, Harsh JB, Flury M, Lukens WW, Pierce EM, Environ. Sci. Technol., 48(21), 12851 (2014)
Evans HT, J. Am. Chem. Soc., 90, 3275 (1968)
Langmuir I, J. Am. Chem. Soc., 38(11), 2221 (1916)
Sips R, J. Chem. Phys., 16(5), 490 (1948)
Afkhami A, Norooz-Asl R, Colloids Surf. A: Physicochem. Eng. Asp., 346(1-3), 52 (2009)
Dodbiba G, Fujita T, Kikuchi T, Manjanna J, Matsuo S, Takahashi H, Tohji K, Chem. Eng. J., 166(2), 496 (2011)
Agarwal S, Tyagi I, Gupta VK, Hanifpour F, Maghsudi M, Javadian H, J. Mol. Liq., 218, 346 (2016)
Zhang B, Liu HZ, Wang W, Gao ZG, Cao YH, Hydrometallurgy, 173, 50 (2017)
Li YH, Yang LJ, Liu XY, Li N, Zhang L, Li Q, Yang Y, Duan Y, Zhang FQ, J. Mater. Sci., 50(18), 5960 (2015)
Seo SY, Choi WS, Yang TJ, Kim MJ, Tran T, Hydrometallurgy, 129-130, 145 (2012)

[1] Pap S, Radonic J, Trifunovic S, Adamovic D, Mihajlovic I, Miloradov MV, Sekulic MT, J. Environ. Manage., 184, 297 (2016)

[2] Sellaoui L, Soetaredjo FE, Ismadji S, Bonilla-Petriciolet A, Belver C, Bedia J, Ben Lamine A, Erto A, Chem. Eng. J., 354, 569 (2018)

[3] Ma J, Qin G, Zhang Y, Sun J, Wang S, Jiang L, J. Clean Prod., 182, 776 (2018)

[4] Lu F, Astruc D, Coord. Chem. Rev., 356, 147 (2018)

[5] Li J, Chen M, Gao Z, Du J, Yang W, Yin M, Colloids Surf. B: Biointerfaces, 146, 468 (2016)

[6] Rumenapp C, Gleich B, Mannherz HG, Haase A, J. Magn. Magn. Mater., 380, 271 (2015)

[7] de Vries JW, Schnichels S, Hurst J, Strudel L, Gruszka A, Kwak M, Bartz-Schmidt KU, Spitzer MS, Herrmann A, Biomaterials, 157, 98 (2018)

[8] Kroger APP, Paulusse JMJ, J. Control. Release, 286, 326 (2018)

[9] Yousefi T, Khanchi AR, Ahmadi SJ, Rofouei MK, Yavari R, Davarkhah R, Myanji B, J. Hazard. Mater., 215-216, 266 (2012)

[10] Chowdhury SR, Yanful EK, Pratt AR, J. Hazard. Mater., 235-236, 246 (2012)

[11] Jiang WJ, Pelaez M, Dionysiou DD, Entezari MH, Tsoutsou D, O'Shea K, Chem. Eng. J., 222, 527 (2013)

[12] Cendrowski K, Sikora P, Zielinska B, Horszczaruk E, Mijowska E, Appl. Surf. Sci., 407, 391 (2017)

[13] Yazdani F, Fattahi B, Azizi N, J. Magn. Magn. Mater., 406, 207 (2016)

[14] Aljarrah MT, Al-Harahsheh MS, Mayyas M, Alrebaki M, J. Environ. Chem. Eng., 6(5), 5662 (2018)

[15] Stober W, Fink A, J. Colloid Interface Sci., 26, 62 (1968)

[16] Suuronen J, Pitkanen I, Halttunen H, Moilanen R, J. Therm. Anal. Calorim., 69(1), 359 (2002)

[17] Roca AG, Marco JF, Morales MP, Serna CJ, J. Phys. Chem. C, 111(13), 18577 (2007)

[18] Arevalo P, Isasi J, Caballero AC, Marco JF, Martin-Hernandez F, Ceram. Int., 43(13), 10333 (2017)

[19] Grosvenor AP, Kobe BA, Biesinger MC, McIntyre NC, Surf. Interface Anal., 36(12), 1564 (2004)

[20] Yamashita T, Hayes P, Appl. Surf. Sci., 254(8), 2441 (2008)

[21] Monti M, Santos B, Mascaraque A, de la Fuente OR, Nino MA, Mentes TO, Locatelli A, McCarty KF, Marco JF, de la Figuera J, J. Phys. Chem. C, 116(21), 11539 (2012)

[22] Gracia M, Marco JF, Gancedo JR, Exel W, Meisel W, Surf. Interface Anal., 29(1), 82 (2000)

[23] Alfonsetti R, De Simone G, Lozzi L, Passacantando M, Picozzi P, SiO SS, Surf. Interface Anal., 22, 89 (1994)

[24] Li K, Zeng Z, Xiong J, Yan L, Guo H, Liu S, Dai Y, Chen T, Colloids Surf. A: Physicochem. Eng. Asp., 465, 113 (2015)

[25] Cao W, Wang ZQ, Zeng QL, Shen CH, Appl. Surf. Sci., 389, 404 (2016)

[26] Viertorinne M, Valkonen J, Pitkanen I, Mathlouthi M, Nurmi J, J. Mol. Struct., 477(1-3), 23 (1999)

[27] Morel M, Martinez F, Mosquera E, J. Magn. Magn. Mater., 343, 76 (2013)

[28] Abbas M, Rao BP, Islam MN, Naga SM, Takahashi M, Kim C, Ceram. Int., 40(1), 1379 (2014)

[29] Matharu K, Mittal SK, Kumar SKA, Sahoo SK, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 145, 165 (2015)

[30] Thurm S, Odenbach S, Phys. Fluids, 15(6), 1658 (2003)

[31] Tadyszak K, Kertmen A, Coy E, Andruszkiewicz R, Milewski S, Kardava I, Scheibe B, Jurga S, Chybczynska K, J. Magn. Magn. Mater., 433, 254 (2017)

[32] Hui C, Shen C, Tian J, Bao L, Ding H, Li C, Tian Y, Shi X, Gao HJ, Nanoscale, 3(2), 701 (2011)

[33] Salmimies R, Vehmaanpera P, Hakkinen A, Hydrometallurgy, 163, 91 (2016)

[34] Vajo JJ, Aikens DA, Ashley L, Poeltl DE, Bailey RA, Clark HM, Bunce SC, Inorg. Chem., 20(10), 3328 (1981)

[35] Ho YS, McKay G, Process Saf. Environ. Protect., 76(4), 332 (1998)

[36] Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)

[37] Sen Gupta S, Bhattacharyya KG, Adv. Colloid Interface Sci., 162, 39 (2011)

[38] Wu FC, Tseng RL, Juang RS, Chem. Eng. J., 150(2-3), 366 (2009)

[39] Dickson JO, Harsh JB, Flury M, Lukens WW, Pierce EM, Environ. Sci. Technol., 48(21), 12851 (2014)

[40] Evans HT, J. Am. Chem. Soc., 90, 3275 (1968)

[41] Langmuir I, J. Am. Chem. Soc., 38(11), 2221 (1916)

[42] Sips R, J. Chem. Phys., 16(5), 490 (1948)

[43] Afkhami A, Norooz-Asl R, Colloids Surf. A: Physicochem. Eng. Asp., 346(1-3), 52 (2009)

[44] Dodbiba G, Fujita T, Kikuchi T, Manjanna J, Matsuo S, Takahashi H, Tohji K, Chem. Eng. J., 166(2), 496 (2011)

[45] Agarwal S, Tyagi I, Gupta VK, Hanifpour F, Maghsudi M, Javadian H, J. Mol. Liq., 218, 346 (2016)

[46] Zhang B, Liu HZ, Wang W, Gao ZG, Cao YH, Hydrometallurgy, 173, 50 (2017)

[47] Li YH, Yang LJ, Liu XY, Li N, Zhang L, Li Q, Yang Y, Duan Y, Zhang FQ, J. Mater. Sci., 50(18), 5960 (2015)

[48] Seo SY, Choi WS, Yang TJ, Kim MJ, Tran T, Hydrometallurgy, 129-130, 145 (2012)