Let G be a semimartingale and S its Snell envelope. Under the assumption that G is an element of H-1, we show that the finite-variation part of S is absolutely continuous with respect to the decreasing part of the finite-variation part of G. In the Markovian setting, this enables us to identify sufficient conditions for the value function of the optimal stopping problem to belong to the domain of the extended (martingale) generator of the underlying Markov process. We then show that the dual of the optimal stopping problem is a stochastic control problem for a controlled Markov process, and the optimal control is characterized by a function belonging to the domain of the martingale generator. Finally, we give an application to the smooth pasting condition.