Chemical Engineering & Technology, Vol.42, No.7, 1481-1491, 2019
Crystallization Mechanisms and Rates of Cyclopentane Hydrates Formation in Brine
Clathrate hydrates most often grow at the interface between liquid water and another fluid phase (hydrocarbon) acting as a provider for the hydrate guest molecules, and some transfer through this shell is required for the hydrate growth to proceed, thus self-limiting the reaction rate. An optical microscope and a horizontal reaction cell are utilized to capture the shell growth phenomenology and to estimate the hydrate layer growth rates from sequential pictures. Cyclopentane (CP) is chosen as the hydrate-forming molecule to obtain hydrates at low pressure. Experimental hydrate layer growth rates are provided for the CP+brine system, using various combinations of salts and degrees of subcooling.