We have investigated the structure of five disilicate glass compositions-K2O . 2SiO(2), (Na0.25K0.75)(2)O . 2SiO(2,) (Na0.50K0.50)(2)O . 2SiO(2), (Na0.75K0.25)(2)O . 2SiO(2,) and Na2O . 2SiO(2)-using 2D O-17 Dynamic Angle Spinning (DAS) Nuclear Magnetic Resonance (NMR). The nonbridging and bridging oxygen sites can be resolved in the isotropic O-17 DAS spectrum. The bridging oxygen isotropic resonance shifts from 16.1 ppm in K2O . 2SiO(2) to 11.8 ppm in Na2O . 2SiO(2) and remains almost identical in width. The nonbridging oxygen isotropic line shapes in the mixed compositions are broader with a maximum intensity that continuously shifts from the position found in the pure potassium composition to the position found in the pure sodium composition. The evolution of the nonbridging oxygen isotropic line shape with changing alkali composition is consistent with a model of the glass structure where four alkali cations are distributed in random combinations around each nonbridging oxygen.