화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.77, 135-145, September, 2019
DOI10.1016/j.jiec.2019.04.028  Export Citation
Study on maximizing catalytic performance of cobalt(II) 5,10,15, 20-tetrakis(4-pyridyl)porphyrin for cyclohexane oxidation
Xian-Fei Huang1, 2, †, Guang-Ping Yuan1, Guan Huang1, †, and Su-Juan Wei1
  • 1School of Computer and Electronic Information, and School of Chemistry and Chemical Engineering, Guangxi University, 530004, Nanning, Guangxi, PR China
  • 2Guangxi Vocational College of Technology and Business, 530008, Nanning, Guangxi, PR China
E-mail:,
Aiming at the most enhancing the catalytic performance of simple and cheap cobalt(II) 5,10,15,20-tetrakis (4-pyridyl)porphyrin (Co TPyP), guided by the nowadays-advanced various technologies, Co TPyP was anchored onto nanoporous bar with thiol-functionalized silica (npb-SiO2-SH). The resulting npb-SiO2-SCo TPyP catalyst was characterized using various techniques, determining its structure. The total surface area ratios (TSAR) of the immobilized cobalt porphyrin to the npb-SiO2-SH, and the catalytic cyclohexane oxidation reaction conditions were at the same time optimized via Response Surface Methodology (RSM). Compared with those obtained from traditional optimizing method (TOM), on average, RSM could enhance as high as more than 60% catalyst turnover frequency (TOF) and yields of cyclohexanone and cyclohexanol (KA oil). The anchored 0.05 mg Co TPyP could catalyze the oxidation of 200 mL of cyclohexane, under not using any solvents and additives, offering 2.5 x 10 6 1/h of TOF, and 19% of yields.The npb-SiO2-S (20%-0.0438)-Co TPyP catalyst showed better reusability, excellent catalytic.
Keywords:Anchored cobalt porphyrin;Thiol-functionalized silica;Cyclohexane oxidation;Response Surface Methodology;Traditional optimizing method
  1. Xu SD, Li HX, Du J, Tang JH, Wang L, ACS Sustain. Chem. Eng., 6, 6418 (2018)
  2. Hong Y, Sun DL, Fang YX, Chem. Cent. J., 12, 36 (2018)
  3. Khare S, Shrivastava P, Chokhare R, Kirar JS, Parashar S, J. Porous Mater., 24, 855 (2017)
  4. Sun W, Gao LF, Feng X, Sun X, Zheng GX, Eur. J. Org. Chem., 1121 (2018).
  5. Sammah N, Ghiaci M, Ind. Eng. Chem. Res., 56(38), 10597 (2017)
  6. Tan XL, Wang XQ, Liu QQ, Zhou J, Zhang PP, Zheng SD, Miao SD, Int. J. Hydrog. Energy, 42(30), 19001 (2017)
  7. Zioueche A, Cherif-Aouali L, Bengueddach A, J. Porous Mater., 26, 575 (2019)
  8. Ribeiro APC, Martins LMDRS, Kuznetsov ML, Pombeiro AJL, Organometallics, 36, 192 (2017)
  9. Antonangelo AR, Benzzu CG, Mughal SS, Malewschik T, Mckeown NB, Nakagaki S, Catal. Commun., 99, 100 (2017)
  10. Rezaei M, Chermahini AN, Dabbagh HA, Chem. Eng. J., 314, 515 (2017)
  11. Xiao YP, Liu JC, Mai JJ, Pan CQ, Cai XL, Fang YX, J. Colloid Interface Sci., 516, 172 (2018)
  12. Seo KJ, KiM HY, Lee JW, Kim MG, Seo SY, KiM CI, J. Ind. Eng. Chem., 53, 371 (2017)
  13. Sawatari N, Yokota T, Sakaguchi S, Ishii Y, J. Org. Chem., 66, 7889 (2001)
  14. de Araujo Torres MG, da Silva VS, Idemori YM, De Freitas-Silva G, Arabian J. Chem. (2017).
  15. Li YJ, Liu CR, Yang WJ, New J. Chem., 41, 8214 (2017)
  16. Ucoski GM, Pinto VHS, De Freitas-Silva G, Reboucas JS, da Silva RM, Mazzaro I, Nunes FS, Nakagaki S, Microporous Mesoporous Mater., 265, 84 (2018)
  17. Barbosa IA, de Sousa PC, da Silva DL, Zanardi FB, Zanatta LD, de Oliveira AJA, Serra OA, Iamamoto Y, J. Colloid Interface Sci., 469, 296 (2016)
  18. Zanardi FB, Barbosa IA, de Sousa Filho PC, Zanatta LD, da Silva DL, Serra OA, Iamamoto Y, Microporous Mesoporous Mater., 219, 161 (2016)
  19. Huang G, Liu Y, Cai JL, Chen XF, Zhao SK, Guo YA, Wei SJ, Li X, Appl. Surf. Sci., 402, 436 (2017)
  20. Huang G, Wang WL, Ning XX, Liu Y, Zhao SK, Guo YA, Wei SJ, Zhou H, Ind. Eng. Chem. Res., 55(11), 2959 (2016)
  21. Bagherzadeh M, Mortazavi-Manesh A, RSC Adv., 6, 41551 (2016)
  22. Zhao P, Liu MC, Zheng M, Jin SF, Tang DT, Lin JQ, Ma YN, Chen J, Liu HJ, J. Nanosci. Nanotechnol., 16, 9843 (2016)
  23. Nejabat F, Rayati S, J. Ind. Eng. Chem., 69, 324 (2019)
  24. Sulaiman NF, Abu Bakar WAW, Ali R, Renew. Energy, 113, 697 (2017)
  25. Sun Y, Yang G, Wen C, Zhang L, Sun Z, J. CO2 Util., 24, 10 (2018)
  26. Senobari S, Nezamzadeh-Ejhieh AA, J. Mol. Liq., 257, 173 (2018)
  27. Ghafuri H, Mohammadi F, Rahimi R, Mohammadiyan E, RSC Adv., 6, 83947 (2016)
  28. Lai CY, Trewyn BG, Jeftinija DM, Jeftinija K, Xu S, Jeftinija S, Lin VSY, J. Am. Chem. Soc., 125(15), 4451 (2003)
  29. Boeckl MS, Bramblett AL, Hauch KD, Sasaki T, Ratner BD, Rogers JW, Langmuir, 16(13), 5644 (2000)
  30. Datta-Gupta N, J. Coord. Chem., 5, 201 (1976)
  31. Machado GS, Castro KADF, Wypych F, Nakagaki S, J. Mol. Catal. A-Chem., 283(1-2), 99 (2008)
  32. Machado GS, Arizaga GGC, Wypych F, Nakagaki S, J. Catal., 274(2), 130 (2010)
  33. Standeker S, Veronovski A, Novak Z, Knez Z, Desalination, 269(1-3), 223 (2011)
  34. Ibrahim MM, Mersal GAM, El-Shafai N, Youssef MM, Shokry H, C.R. Chim., 17, 1013 (2014)
  35. Jiang LQ, Cui LL, He XQ, J. Solid State Electrochem., 19, 497 (2015)
  36. Gulino A, Anal. Bioanal. Chem., 405, 1479 (2013)
  37. Bach LG, Islam MR, Jeong YT, Hwang HS, Lim KT, Mol. Cryst. Liq. Cryst., 565, 78 (2012)
  38. Solomon EI, Clendening PJ, Gray HB, J. Am. Chem. Soc., 97, 3878 (1975)
  39. Zhu MH, Chen JC, Huang LB, Ye RQ, Xu J, Han YF, Angew. Chem.-Int. Edit., 58, 1 (2019)
  40. Tang HJ, Yin HJ, Wang JY, Yang NL, Wang D, Tang ZY, Angew. Chem.-Int. Edit., 125, 5695 (2013)
  41. Nguyen HC, Liang SH, Doan TT, Su CH, Yang PC, Energy Conv. Manag., 145, 335 (2017)
  42. Hermans I, Peeters J, Jacobs PA, J. Org. Chem., 72, 3057 (2007)
  43. Evans S, Smith JRL, J. Chem. Soc.-Perkin Trans. 1, 2, 174 (2001)
  44. Feng Z, Xie YJ, Hao F, Liu PL, Luo HA, RSC Adv., 5, 101593 (2015)
  45. Chang CJ, Loh ZH, Shi CN, Anson FC, Nocera DG, J. Am. Chem. Soc., 126(32), 10013 (2004)