Analysis of crystal phases of Na+-β/β"-alumina/YSZ composite prepared by vapor-phase synthesis from YSZ-toughened α-alumina

Dae-Han Lee; Sang-Soo Han; Young-Hyuk Kim; Sung-Ki Lim

Journal of Industrial and Engineering Chemistry, Vol.76, 366-373, August, 2019

DOI10.1016/j.jiec.2019.04.002 Export Citation

Analysis of crystal phases of Na+-β/β"-alumina/YSZ composite prepared by vapor-phase synthesis from YSZ-toughened α-alumina

Dae-Han Lee, Sang-Soo Han, Young-Hyuk Kim, and Sung-Ki Lim^†

Department of Materials Chemistry and Engineering, Konkuk University, 120, Neungdong-ro, Gwangjin-gu, Seoul 143-701, South Korea

E-mail:

Crystal phases of Na+-β/β"-alumina electrolytes prepared by vapor-phase synthesis to resolve problems associated with solid-state reaction (i.e., Na2O loss at high sintering temperature and limitation to reducing the thickness) were analyzed. Na+-β/β"-alumina/YSZ composite was prepared by α- to β/β"- alumina phase conversion using sodium aluminate (i.e. Na2O source) from a α-alumina/YSZ sintered sample by vapor-phase synthesis. A fabricated Na+-β/β"-alumina fully crystalized without any secondary phase. Its bulk density increased with increasing YSZ content. A maximum ionic conductivity of 1.8 x 10-2 S/cm at 350 °C was obtained from a 50 wt.% YSZ-added specimen converted at 1500 °C for four hours.

Keywords:Na+-β/β"-alumina;YSZ (Yttria-Stabilized Zirconia)-toughened;alumina;Na-based batteries;Vapor-Phase synthesis

[References]

Doughty DH, Butler PC, Akhil AA, Clark NH, Boyes JD, J. Electrochem. Soc., 19, 49 (2010)
Yang ZG, Zhang JL, Kintner-Meyer MCW, Lu XC, Choi DW, Lemmon JP, Liu J, Chem. Rev., 111(5), 3577 (2011)
Sudworth JL, Tilley AR, The Sodium-Sulfur Battery, Chapman and Hall, London, England, pp.19 1985.
Sudworth JL, Tilley AR, The Sodium-Sulfur Battery, Chapman and Hall, London, England, pp.141 1985.
Engstrom H, Bates JB, Brundage WE, Wang JC, Solid State Ion., 2(4), 265 (1981)
Yao YFY, Kummer JT, J. Inorg. Nucl. Chem., 29(9), 2453 (1967)
Certo J, Furtado CS, Ferreira AJ, Perdigao JM, Ionics, 4, 124 (1998)
Fally J, Lasne C. Lazennec Y, Margotin P, J. Electrochem. Soc., 120(10), 1292 (1973)
Yamaguchi G, Suzuki K, Bull. Chem. Soc. Jpn., 41, 93 (1968)
Yamaguchi G, J. Electrochem. Soc. Japan, 18, 260 (1943)
Youngblood GE, Virkar AV, Cannon WR, Gordon RS, Bull. Amer. Ceram. Soc., 56(2), 206 (1977)
Van Zyl A, Thackeray MM, Duncan GK, Kingon AI, Heckroodt RO, Mater. Res. Bull., 28(2), 145 (1993)
Virkar AV, Jue JF, Fung KZ, Alkali Metal Beta and Beta" Alumina and Gallate Polycrystalline Ceramics and Fabrication by a Vapor Phase Process, U. S. Patent No. 6117807, September 12, 2000.
Parthasarathy P, Weber N, Virkar AV, ECS Trans., 6(14), 67 (2007)
Han MF, Tang XL, Yin HY, Peng SP, J. Power Sources, 165(2), 757 (2007)
Liu M, Lynch ME, Blinn K, Alamgir FM, Choi YM, Materials Today, 14(11), 534 (2011)
de Souza S, Visco SJ, De Jonghe LC, J. Electrochem. Soc., 144, L35 (1997)
Eichler A, Physical Review B, 64, 174103 (2001)
Pascual C, Jurado JR, Duran P, J. Mater. Sci., 18(5), 1315 (1983)
Parthasarathy P, Virkar AV, J. Electrochem. Soc., 160(11), A2268 (2013)
Ghadbeigi L, Szendrei A, Moreno P, Sparks TD, Virkar AV, Solid State Ion., 290, 77 (2016)
Mori M, Abe T, Itoh H, Yamamoto O, Takeda Y, Kawahara T, Solid State Ion., 74(3-4), 157 (1994)
Oe KI, Kikkawa K, Kishimoto A, Nakamura Y, Yanagida H, Solid State Ion., 91(1-2), 131 (1996)
Peters A, Korte C, Hesse D, Zakharov N, Janek J, Solid State Ion., 178(1-2), 67 (2007)
Lee JH, Lee JH, Jung YS, Kim DY, J. Am. Ceram. Soc., 86(9), 1518 (2003)
Lange FF, Davis BI, Raleigh DO, J. Am. Ceram. Soc., 66(3), C50 (1983)
Green DJ, J. Mater. Sci., 20(7), 2639 (1985)
Virkar AV, J. Mater. Sci., 16(5), 1142 (1981)
Lu X, Xia G, Lemmon JP, Yang Z, J. Power Sources, 198(9), 2431 (2010)
Sparksa TD, Ghadbeigi L, J. Mater. Res., 33(1), 81 (2018)
Schmid C, J. Mater. Sci. Lett., 5(3), 263 (1986)
Lee ST, Kim SG, Jang MH, Hwang SH, Haw JR, Lim SK, J. Ceram. Pro. Res., 11(1), 86 (2010)
Xu D, Jiang H, Li M, Hai O, Zhang Y, Ceram. Int., 41, 5355 (2015)
Olson D, De Jonghe LC, J. Mater. Sci., 21(12), 4221 (1986)
Casellas D, Nagl MM, Llanes L, Anglada M, J. Am. Ceram. Soc., 88(7), 1958 (2005)

[1] Doughty DH, Butler PC, Akhil AA, Clark NH, Boyes JD, J. Electrochem. Soc., 19, 49 (2010)

[2] Yang ZG, Zhang JL, Kintner-Meyer MCW, Lu XC, Choi DW, Lemmon JP, Liu J, Chem. Rev., 111(5), 3577 (2011)

[3] Sudworth JL, Tilley AR, The Sodium-Sulfur Battery, Chapman and Hall, London, England, pp.19 1985.

[4] Sudworth JL, Tilley AR, The Sodium-Sulfur Battery, Chapman and Hall, London, England, pp.141 1985.

[5] Engstrom H, Bates JB, Brundage WE, Wang JC, Solid State Ion., 2(4), 265 (1981)

[6] Yao YFY, Kummer JT, J. Inorg. Nucl. Chem., 29(9), 2453 (1967)

[7] Certo J, Furtado CS, Ferreira AJ, Perdigao JM, Ionics, 4, 124 (1998)

[8] Fally J, Lasne C. Lazennec Y, Margotin P, J. Electrochem. Soc., 120(10), 1292 (1973)

[9] Yamaguchi G, Suzuki K, Bull. Chem. Soc. Jpn., 41, 93 (1968)

[10] Yamaguchi G, J. Electrochem. Soc. Japan, 18, 260 (1943)

[11] Youngblood GE, Virkar AV, Cannon WR, Gordon RS, Bull. Amer. Ceram. Soc., 56(2), 206 (1977)

[12] Van Zyl A, Thackeray MM, Duncan GK, Kingon AI, Heckroodt RO, Mater. Res. Bull., 28(2), 145 (1993)

[13] Virkar AV, Jue JF, Fung KZ, Alkali Metal Beta and Beta" Alumina and Gallate Polycrystalline Ceramics and Fabrication by a Vapor Phase Process, U. S. Patent No. 6117807, September 12, 2000.

[14] Parthasarathy P, Weber N, Virkar AV, ECS Trans., 6(14), 67 (2007)

[15] Han MF, Tang XL, Yin HY, Peng SP, J. Power Sources, 165(2), 757 (2007)

[16] Liu M, Lynch ME, Blinn K, Alamgir FM, Choi YM, Materials Today, 14(11), 534 (2011)

[17] de Souza S, Visco SJ, De Jonghe LC, J. Electrochem. Soc., 144, L35 (1997)

[18] Eichler A, Physical Review B, 64, 174103 (2001)

[19] Pascual C, Jurado JR, Duran P, J. Mater. Sci., 18(5), 1315 (1983)

[20] Parthasarathy P, Virkar AV, J. Electrochem. Soc., 160(11), A2268 (2013)

[21] Ghadbeigi L, Szendrei A, Moreno P, Sparks TD, Virkar AV, Solid State Ion., 290, 77 (2016)

[22] Mori M, Abe T, Itoh H, Yamamoto O, Takeda Y, Kawahara T, Solid State Ion., 74(3-4), 157 (1994)

[23] Oe KI, Kikkawa K, Kishimoto A, Nakamura Y, Yanagida H, Solid State Ion., 91(1-2), 131 (1996)

[24] Peters A, Korte C, Hesse D, Zakharov N, Janek J, Solid State Ion., 178(1-2), 67 (2007)

[25] Lee JH, Lee JH, Jung YS, Kim DY, J. Am. Ceram. Soc., 86(9), 1518 (2003)

[26] Lange FF, Davis BI, Raleigh DO, J. Am. Ceram. Soc., 66(3), C50 (1983)

[27] Green DJ, J. Mater. Sci., 20(7), 2639 (1985)

[28] Virkar AV, J. Mater. Sci., 16(5), 1142 (1981)

[29] Lu X, Xia G, Lemmon JP, Yang Z, J. Power Sources, 198(9), 2431 (2010)

[30] Sparksa TD, Ghadbeigi L, J. Mater. Res., 33(1), 81 (2018)

[31] Schmid C, J. Mater. Sci. Lett., 5(3), 263 (1986)

[32] Lee ST, Kim SG, Jang MH, Hwang SH, Haw JR, Lim SK, J. Ceram. Pro. Res., 11(1), 86 (2010)

[33] Xu D, Jiang H, Li M, Hai O, Zhang Y, Ceram. Int., 41, 5355 (2015)

[34] Olson D, De Jonghe LC, J. Mater. Sci., 21(12), 4221 (1986)

[35] Casellas D, Nagl MM, Llanes L, Anglada M, J. Am. Ceram. Soc., 88(7), 1958 (2005)