화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.27, No.6, 526-533, June, 2019
DOI10.1007/s13233-019-7080-x  Export Citation
Dual-Responsive Shape Memory and Thermally Reconfigurable Reduced Graphene Oxide-Vitrimer Composites
Guo-kang Chen1, 2, Kun Wu1, 2, Qian Zhang2, Yan-cen Shi2, and Man-geng Lu1, 2, †
  • 1Key Laboratory of Cellulose and Lignocellulosics Chemistry, Guangzhou institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, P. R. China
  • 2University of Chinese Academy of Sciences, Beijing 100039, P. R. China
E-mail:
In this paper, we have prepared shape memory reduced graphene oxide-vitrimer composites via in situ reduction of graphene oxide (GO) during the curing reaction. Because of good compatibility between GO and epoxy resin, reduced graphene oxide (rGO) has a good dispersion in the epoxy matrix. Conventional thermoset shape memory polymers can only maintain one permanent shape, while these obtained composites can be randomly reconfigured into other shapes via dynamic covalent transesterification reaction at 200 °C above transesterification temperature (TV). They can recover quickly from fixed shapes to their initial shapes with shape fixity ratio higher than 95% and shape recovery ratio higher than 97%. Besides, the rGO-vitrimers show good mechanical properties and thermal stabilities. In addition, sequent near-infrared (NIR) irradiation can control the shape recovery, because rGO can serve as an energy convertor to convert NIR irradiation into thermal energy.
Keywords:vitrimers;shape memory polymer;reduced graphene oxide
  1. Habault D, Zhang H, Zhao Y, Chem. Soc. Rev., 42, 7244 (2013)
  2. Ishii S, Uto K, Niiyama E, Ebara M, Nagao T, ACS Appl. Mater. Interfaces, 8, 5634 (2016)
  3. Huang WM, Yang B, Zhao Y, Ding Z, J. Mater. Chem., 20, 3367 (2010)
  4. Huang WM, Yang B, An L, Li C, Chan YS, Appl. Phys. Lett., 86 (2005)
  5. Schmaljohann D, Adv. Drug Deliv. Rev., 58, 1655 (2006)
  6. Lendlein A, Kelch S, Angew. Chem.-Int. Edit., 41, 2034 (2002)
  7. Mather PT, Luo X, Rousseau IA, Annu. Rev. Mater. Res., 39 (2009)
  8. Gopishetty V, Roiter Y, Tokarev I, Minko S, Adv. Mater., 20(23), 4588 (2008)
  9. Zhang YL, Tao L, Li SX, Wei Y, Biomacromolecules, 12(8), 2894 (2011)
  10. He ZW, Satarkar N, Xie T, Cheng YT, Hilt JZ, Adv. Mater., 23(28), 3192 (2011)
  11. Kumar UN, Kratz K, Wagermaier W, Behl M, Lendlein A, J. Mater. Chem., 20, 3404 (2010)
  12. Xie X, Qu L, Zhou C, Li Y, Zhu J, Bai H, Shi G, Dai L, ACS Nano, 4, 6050 (2010)
  13. Osada Y, Okuzaki H, Hori H, Nature, 355, 242 (1992)
  14. Fritzsche N, Pretsch T, Macromolecules, 47(17), 5952 (2014)
  15. Ecker M, Pretsch T, RSC Adv., 4, 46680 (2014)
  16. Navarro-Baena I, Kenny JM, Peponi L, Cellulose, 21, 4231 (2014)
  17. Saralegi A, Luz Gonzalez M, Valea A, Eceiza A, Corcuera MA, Compos. Sci. Technol., 92, 27 (2014)
  18. Qiu Y, Park K, Adv. Drug Deliv. Rev., 64, 49 (2012)
  19. Roesler A, Vandermeulen GWM, Klok HA, Adv. Drug Deliv. Rev., 64, 270 (2012)
  20. Sun L, Huang WM, Wang CC, Ding Z, Zhao Y, Tang C, Gao XY, Liq. Cryst., 41, 277 (2014)
  21. Bothe M, Pretsch T, J. Mater. Chem. A, 1, 14491 (2013)
  22. Khaldi A, Elliott JA, Smoukov SK, J. Mater. Chem. C, 2, 8029 (2014)
  23. Sun L, Huang WM, Lu HB, Wang CC, Zhang JL, Assembly Autom., 34, 78 (2014)
  24. Liu Y, Du H, Liu L, Leng J, Smart Mater. Struct., 23 (2014)
  25. Behl M, Lendlein A, Mater. Today, 10, 20 (2007)
  26. Michal BT, Jaye CA, Spencer EJ, Rowan SJ, ACS Macro Lett., 2, 694 (2013)
  27. Guo H, Li Y, Zheng J, Gan J, Liang L, Wu K, Lu M, RSC Adv., 5, 67247 (2015)
  28. Yoonessi M, Shi Y, Scheiman DA, Lebron-Colon M, Tigelaar DM, Weiss RA, Meador MA, ACS Nano, 6, 7644 (2012)
  29. Wang Q, Bai Y, Chen Y, Ju J, Zheng F, Wang T, J. Mater. Chem. A, 3, 352 (2015)
  30. Xiao XL, Kong DY, Qiu XY, Zhang WB, Zhang FH, Liu LW, Liu YJ, Zhang S, Hu Y, Leng JS, Macromolecules, 48(11), 3582 (2015)
  31. Lawton MI, Tillman KR, Mohammed HS, Kuang W, Shipp DA, Mather PT, ACS Macro Lett., 5, 203 (2016)
  32. Yang Z, Wang Q, Wang T, ACS Appl. Mater. Interfaces, 8, 21691 (2016)
  33. Zhao Q, Zou W, Luo Y, Xie T, Sci. Adv., 2 (2016)
  34. Yang Y, Pei ZQ, Li Z, Wei Y, Ji Y, J. Am. Chem. Soc., 138(7), 2118 (2016)
  35. Pei ZQ, Yang Y, Chen QM, Wei Y, Ji Y, Adv. Mater., 28(1), 156 (2016)
  36. Kissounko DA, Taynton P, Kaffer C, Reinforced Plast., 62, 162 (2018)
  37. Pei ZQ, Yang Y, Chen QM, Terentjev EM, Wei Y, Ji Y, Nat. Mater., 13(1), 36 (2014)
  38. Montarnal D, Capelot M, Tournilhac F, Leibler L, Science, 334(6058), 965 (2011)
  39. Bortz DR, Heras EG, Martin-Gullon I, Macromolecules, 45(1), 238 (2012)
  40. Amirova L, Surnova A, Balkaev D, Musin D, Amirov R, Dimiev AM, ACS Appl. Mater. Interfaces, 9, 11909 (2017)
  41. Moosaei R, Sharif M, Ramezannezhad A, Polym. Test, 60, 173 (2017)
  42. Kulkarni DD, Choi I, Singamaneni S, Tsukruk VV, ACS Nano, 4, 4667 (2010)
  43. Yu L, Cheng Z, Dong Z, Zhang Y, Yu H, J. Mater. Chem. C, 2, 8501 (2014)
  44. Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS, Adv. Mater., 22(35), 3906 (2010)
  45. Cheng Z, Wang T, Li X, Zhang Y, Yu H, ACS Appl. Mater. Interfaces, 7, 27494 (2015)
  46. Huang JH, Zhao L, Wang T, Sun WX, Tong Z, ACS Appl. Mater. Interfaces, 8, 12384 (2016)
  47. Ren SP, Liang LY, Lan YX, Lu MG, J. Appl. Polym. Sci., 106(5), 2917 (2007)
  48. Tang H, Ehlert GJ, Lin Y, Sodano HA, Nano Lett., 12, 84 (2012)
  49. Jeong HK, Lee YP, Jin MH, Kim ES, Bae JJ, Lee YH, Chem. Phys. Lett., 470(4-6), 255 (2009)
  50. Yang Y, Pei Z, Zhang X, Tao L, Wei Y, Ji Y, Chem. Sci., 5, 3486 (2014)
  51. Capelot M, Unterlass MM, Tournilhac F, Leibler L, ACS Macro Lett., 1, 789 (2012)
  52. Capelot M, Montarnal D, Tournilhac F, Leibler L, J. Am. Chem. Soc., 134(18), 7664 (2012)
  53. Li Z, Yang Y, Wang Z, Zhang X, Chen Q, Qian X, Liu N, Wei Y, Ji Y, J. Mater. Chem. A, 5, 6740 (2017)
  54. Chen Q, Yu X, Pei Z, Yang Y, Wei Y, Ji Y, Chem. Sci., 8, 724 (2017)
  55. Olowojoba GB, Kopsidas S, Eslava S, Gutierrez ES, Kinloch AJ, Mattevi C, Rocha VG, Taylor AC, J. Mater. Sci., 52(12), 7323 (2017)
  56. Guo H, Lu M, Liang L, Zheng J, Zhang Y, Li Y, Li Z, Yang C, J. Appl. Polym. Sci., 131, 40363 (2014)
  57. khezri T, Sharif M, Pourabas B, RSC Adv., 6, 93680 (2016)