화학공학소재연구정보센터
Journal of the Electrochemical Society, Vol.166, No.6, A1063-A1069, 2019
Rechargeable Zinc-Ion Battery Based on Choline Chloride-Urea Deep Eutectic Solvent
Recently, because of their cost effectiveness, high safety and environmental friendliness, zinc-ion batteries (ZIBs) are receiving enormous attention. Until now, aqueous-based ZIBs have been the focus of attention. However, the issues regarding hydrogen evolution, and zinc electrode passivation as well as dendrite formation limit their practical application. In this work, a biocompatible, stable and low-cost choline chloride/ urea (ChCl/urea) deep eutectic solvent is reported as an alternative electrolyte for rechargeable ZIBs based on delta-type manganese oxide (delta-MnO2) intercalation electrode. The behavior of the zinc electrode on stripping and deposition in ChCl/urea electrolyte was examined. Besides, the charge storage and charge-transfer characteristics of the battery was studied. The results showed that there was no sign of dendrite formation on the zinc electrode during long-term cycling. Consequently, the fabricated battery exhibited good electrochemical performance with the maximum specific capacity of 170 mAh/g and good cyclability. In addition, the system showed reversible plating/stripping of zinc (Zn) without dendrite formation and no passivation layer on the zinc electrode. Hencc. the results confirmed the reversible intercalation of Zn from the deep eutectic solvent ChCl/urea into the delta-MnO2 electrode. Overall, the proposed electrolyte shows good promise for Zn/delta-MnO2 battery system. (C) The Author(s) 2019. Published by ECS.