Emerging solar cell (ESC) carrier's dynamic transfer difficulties and instability at dissimilar material's interface seems to be potential distress. Electrical permittivity influences on photo carrier dynamics of nonpolarized organic and polarized organic-inorganic perovskite solar cell. ESC electrical efficiency and stability are consider to be managed broadly by carrier accumulation, extraction, and conduction techniques. Active materials optoelectric interaction and carrier accumulation are petite known. Its energetic dealings with dissimilar interface materials how support to faster carrier extraction and conduction are still in haze. In this drill, focus on active to interface materials key properties are imperative to find a way to promote electrical energy conversion and its steadiness. Selected advanced interface engineering materials (IEMs) architectures, conduction, and multifarious relations to active materials for efficient energy transfer ability and stability are reported precisely by the model. The interface structure consistency supports to systematize energy transfer, otherwise, disorder or energy loss is anticipated. Therefore, active material linkage to IEM photophysical, quantum, and choice of materials technologies are focused comprehensively to explore the pathway of ESC stability and efficiency progression.