화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.74, 118-125, June, 2019
DOI10.1016/j.jiec.2019.02.016  Export Citation
Enhanced CO2/CH4 selectivity and mechanical strength of mixed-matrix membrane incorporated with NiDOBDC/GO composite
Wen Li1, Chong Yang Chuah1, Lina Nie1, and Tae-Hyun Bae1, 2, †
  • 1School of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore, 637459, Singapore
  • 2Singapore Membrane Technology Centre, Nanyang Technological University, Singapore, 637141, Singapore
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A three-dimensional NiDOBDC/GO composite with an optimized accessible surface area was successfully synthesized and incorporated into a polyimide membrane to improve CO2/CH4 separation performance while keeping good mechanical strength. A significant increase in CO2/CH4 selectivity (59%) was observed for the case of 20% NiDOBDC/GO composite in Matrimid® membrane, without sacrificing CO2 permeability. Furthermore, the incorporation of the NiDOBDC/GO composite in a polymeric membrane was found to improve the overall mechanical strength of resulting mixed-matrix membranes. Therefore, the addition of the nanocomposites as fillers in polymeric membranes is proposed as a promising strategy to realize major improvements in CO2/CH4 separation.
Keywords:Mixed-matrix membrane;Graphene oxide;Metal-organic framework;Polyimide;CO2/CH4 separation
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