화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.74, 86-95, June, 2019
DOI10.1016/j.jiec.2019.02.007  Export Citation
Sintering-resistant Cu/B/Ca/Al2O3 catalysts for durable hydrogenation of sec-butyl acetate to 2-butanol and ethanol
Peiyong Sun, Haixing Wang, Xueqing Luo, Changbin Jia, Shenghong Zhang†, and Zhilong Yao
  • Beijing Key Laboratory of Enze Biomass Fine Chemicals, School of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
E-mail:
Quaternary Cu/B/Ca/Al2O3 catalyst extrudates were prepared and optimized for hydrogenation of sec-butyl acetate (SBA) to 2-butanol and ethanol. The rationally designed catalyst with a B/Cu molar ratio of 3/1 exhibited an extraordinary resistance to Cu sintering during the reaction over 1000?h, due to the enhanced interaction by B2O3 between copper species and support. The slight loss in activity after the long-term test, caused mainly by the partial transformation of surface CaO to calcium acetate, could be easily recovered by calcination and the following reduction treatments, rendering it feasible to apply the catalyst to the industrial hydrogenation of SBA.
Keywords:sec-Butyl acetate;2-Butanol;Hydrogenation;Cu catalyst;Sintering-resistant;Stability
  1. Gehre M, Guo Z, Rothenberg G, Tanase S, ChemSusChem, 10, 3947 (2017)
  2. Tokumoto Y, Sakamoto K, Sasaki K, Shimizu I, US Patent 5457228 (1996).
  3. Yao Z, Sci. Sin. Chim., 44, 114 (2014)
  4. Jia C, Luo X, Sun P, Zhang S, Yao Z, Chin. J. Mol. Catal., 29, 218 (2015)
  5. Sun P, Jia C, Luo X, Zhang S, Yao Z, CIESC J., 1313 (2016).
  6. Sun P, Luo X, Zhang S, Yao Z, Chin. J. Mol. Catal., 30, 226 (2016)
  7. Wang HX, Wu CM, Bu XW, Tang WL, Li L, Qiu T, Chem. Eng. J., 246, 366 (2014)
  8. Yang JB, Zeng T, Cai DR, Li L, Tang WL, Hong RY, Qiu T, Asia Pac. J. Chem. Eng., 11, 901 (2016)
  9. Wu CM, Gao ZY, Wang Y, Luo YB, Chem. Eng. J., 354, 599 (2018)
  10. Chang HF, Yang CF, Ind. Eng. Chem. Res., 36(6), 2080 (1997)
  11. Fang D, Ren W, Liu Z, Xu X, Xu L, Lu H, Liao W, Zhang H, J. Nat. Gas Chem., 18, 179 (2009)
  12. Geravand E, Shariatinia Z, Yaripour F, Sahebdelfar S, Chem. Eng. Res. Des., 96, 63 (2015)
  13. Wang DB, Chem. Ind. Eng. Prog., 33, 1429 (2014)
  14. Liu ZM, Zhu SK, N-butene with direct addition of acetate to acetic acid secbutyl, 2013.
  15. Fichtl MB, Schlereth D, Jacobsen N, Kasatkin I, Schumann J, Behrens M, Schlogl R, Hinrichsen O, Appl. Catal. A: Gen., 502, 262 (2015)
  16. Zheng J, Zhou J, Lin H, Duan X, Williams CT, Yuan Y, J. Phys. Chem. C, 119, 13758 (2015)
  17. Rajkhowa T, Marin GB, Thybaut JW, J. Ind. Eng. Chem., 54, 270 (2017)
  18. Hansen TW, DeLaRiva AT, Challa SR, Datye AK, Accounts Chem. Res., 46, 1720 (2013)
  19. Datye AK, Xu Q, Kharas KC, McCarty JM, Catal. Today, 111(1-2), 59 (2006)
  20. van den Berg R, Parmentier TE, Elkjær CF, Gommes CJ, Sehested J, Helveg S, de Jongh PE, de Jong KP, ACS Catal., 5, 4439 (2015)
  21. Goodman ED, Schwalbe JA, Cargnello M, ACS Catal., 7, 7156 (2017)
  22. Dai Y, Lu P, Cao Z, Campbell CT, Xia Y, Chem. Soc. Rev., 47, 4314 (2018)
  23. Ye RP, Lin L, Li Q, Zhou Z, Wang T, Russell CK, Adidharma H, Xu Z, Yao YG, Fan M, Catal. Sci. Technol., 8, 3428 (2018)
  24. Kasinathan P, Hwang DW, Lee UH, Hwang YK, Chang JS, Catal. Commun., 41, 17 (2013)
  25. Hu Q, Fan GL, Zhang SY, Yang L, Li F, J. Mol. Catal. A-Chem., 397, 134 (2015)
  26. Ye RP, Lin L, Chen CC, Yang JX, Li F, Zhang X, Li DJ, Qin YY, Zhou Z, Yao YG, ACS Catal., 8, 3382 (2018)
  27. Zheng X, Lin H, Zheng J, Duan X, Yuan Y, ACS Catal., 3, 2738 (2013)
  28. Zhu Y, Shi L, J. Ind. Eng. Chem., 20(4), 2341 (2014)
  29. Ye CL, Guo CL, Zhang JL, Fuel Process. Technol., 143, 219 (2016)
  30. Zhu Y, Kong X, Li X, Ding G, Zhu Y, Li YW, ACS Catal., 4, 3612 (2014)
  31. Ding J, Zhang J, Zhang C, Liu KF, Xiao HC, Kong FH, Chen JG, Appl. Catal. A: Gen., 508, 68 (2015)
  32. Huang XM, Ma M, Miao S, Zheng YP, Chen MS, Shen WJ, Appl. Catal. A: Gen., 531, 79 (2017)
  33. Xu C, Chen G, Zhao Y, Liu P, Duan X, Gu L, Fu G, Yuan Y, Zheng N, Nat. Commun., 9, 3367 (2018)
  34. Chen YZ, Chang CL, Catal. Lett., 48(1-2), 101 (1997)
  35. He Z, Lin HQ, He P, Yuan YZ, J. Catal., 277(1), 54 (2011)
  36. Yin AY, Qu JW, Guo XY, Dai WL, Fan KN, Appl. Catal. A: Gen., 400(1-2), 39 (2011)
  37. Zhao S, Yue HR, Zhao YJ, Wang B, Geng YC, Lv J, Wang SP, Gong JL, Ma XB, J. Catal., 297, 142 (2013)
  38. Zhu SH, Gao XQ, Zhu YL, Zhu YF, Zheng HY, Li YW, J. Catal., 303, 70 (2013)
  39. Trueba M, Trasatti SP, Eur. J. Inorg. Chem., 2005, 3393 (2005)
  40. Alonso DM, Mariscal R, Moreno-Tost R, Poves MDZ, Granados ML, Catal. Commun., 8, 2074 (2007)
  41. Kutalek P, Capek L, Smolakova L, Kubicka D, Hajek M, Chin. J. Catal., 35, 1084 (2014)
  42. Bansode A, Tidona B, von Rohr PR, Urakawa A, Catal. Sci. Technol., 3, 767 (2013)
  43. Qin HY, Guo CL, Sun CW, Zhang JL, J. Mol. Catal. A-Chem., 409, 79 (2015)
  44. Tian J, Chen W, Wu P, Zhu Z, Li X, Catal. Sci. Technol, 8, 2624 (2018)
  45. Zhao L, Zhao YJ, Wang SP, Yue HR, Wang B, Lv J, Ma XB, Ind. Eng. Chem. Res., 51(43), 13935 (2012)
  46. Argyle M, Bartholomew C, Catalysts, 5, 145 (2015)
  47. Yu JF, Ge QJ, Fang W, Xu HY, Appl. Catal. A: Gen., 395(1-2), 114 (2011)
  48. Choong CKS, Huang L, Zhong ZY, Lin JY, Hong L, Chen LW, Appl. Catal. A: Gen., 407(1-2), 155 (2011)
  49. Wang Y, Shen YL, Zhao YJ, Lv J, Wang SP, Ma XB, ACS Catal., 5, 6200 (2015)
  50. Chen H, Tan J, Cui J, Yang X, Zheng H, Zhu Y, Li Y, Mol. Catal., 433, 346 (2017)
  51. Witzke ME, Dietrich PJ, Ibrahim MYS, Al-Bardan K, Triezenberg MD, Flaherty DW, Chem. Commun., 53, 597 (2017)
  52. Wu DF, Guo YL, Geng S, Xia YH, Ind. Eng. Chem. Res., 52(3), 1216 (2013)
  53. Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KSW, Pure Appl. Chem., 87, 1051 (2015)
  54. Musumeci AW, Frost RL, Waclawik ER, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 67, 649 (2007)
  55. Tong SR, Wu LY, Ge MF, Wang WG, Pu ZF, Atmos. Chem. Phys., 10, 7561 (2010)
  56. Niu SL, Han KH, Lu CM, Sun RY, Appl. Energy, 87(7), 2237 (2010)
  57. Twigg MV, Spencer MS, Appl. Catal. A: Gen., 212(1-2), 161 (2001)