In this study, rape straw- and corn cob-derived porous carbons (PCs) were fabricated by hydrothermal treatment (250 degrees C, 4 h) and subsequent activation (850 degrees C, 1 h) using a non-corrosive agent, potassium bicarbonate. The PCs exhibited a very large specific surface area (1069-1281 cm(2) g(-1)), high pore volume (0.55-0.72 cm(3) g wide pore size distribution (from micropores to macropores), high hydrophobicity, and partly graphitized structure. These properties contributed to highly efficient performance for the sorption of polycyclic aromatic hydrocarbons (PAHs), with maximum sorption capacities of 592.97, 480.27, and 692.27 mg g(-1) towards naphthalene, acenaphthene, and phenanthrene, respectively. A three-step sorption process with pore filling, hydrophobic effects, and pi-pi stacking interactions on the heterogeneous surface is a possible mechanism for the sorption of PAHs onto PCs. This study presents an environmentally friendly strategy for the reuse of crop residues in the field of organic micropollutant-contaminated water treatment.