화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.27, No.5, 460-469, May, 2019
DOI10.1007/s13233-019-7060-1  Export Citation
Self-Healing and Rheological Properties of Polyhydroxyurethane Elastomers Based on Glycerol Carbonate Capped Prepolymers
Sang Hyub Lee, and Dai Soo Lee†
  • Department of Semiconductor and Chemical Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeonbuk 54896, Korea
E-mail:
Polyhydroxyurethane were prepared from polyurethane prepolymers by end capping with glycerol carbonate (GC) and chain extension with an amine. The GC-based polyurethane (GPU) shows excellent mechanical properties together with superior self-healing properties compared with conventional polyurethane (CPU). The significant improvement in mechanical properties was driven by enhanced hydrogen bonding and the excellent self-healing was attributed to the exchange reaction of the β-hydroxy unit of GPU. The self-healing efficiencies of GPU and CPU were approximately 92% and 42% at 110 °C, respectively. The characteristics of GPU were also studied by rheological measurements. GPU showed not only a negative normal stress difference (N1) but also a crossover of storage (G′) and loss (G″) moduli. It is postulated that the exchange reactions of GPU in melts induce a negative N1 as well as self-healing of the GPU, implying desirable melt processing stability with minimal die swell.
Keywords:polyhydroxyurethane;cyclic carbonate;self-healing;negative normal stress difference;die swell
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