SiOCN ceramic aerogels with lightweight, high surface areas, and macro-meso pores have been synthesized by a facile method combining freeze-drying technique and polymer-derived ceramic route. The wet gels are synthesized via the hydrosilylation reaction between polysilazane and divinylbenzene with cyclohexane as solvent. The solvent is then removed by a freeze-drying process to form pre-ceramic aerogels. The SiOCN ceramic aerogels are finally obtained by pyrolyzing the pre-ceramic aerogels at 1000 degrees C in ultrahigh purity N-2. The thermogravimetric and mass spectrometry system (TG/DSC-MS) is used to investigate the polymer-to-ceramic conversion process during pyrolysis. The phase composition, structure, and morphology of the SiOCN ceramic aerogels are investigated by XRD, FT-IR, XPS, and SEM. The results show that SiOCN ceramic aerogels are composed of amorphous matrix phase and "free carbon" phase. The SiOCN aerogels possess three-dimensional (3D) network porous structure with low density (0.19 g/cm(3)), high specific surface area (134 m(2)/g), large pore volume (0.49 cm(3)/g), and hierarchical pore structures of both macro and meso pores. The formation mechanism and evolution process of SiOCN ceramic aerogels are discussed.