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Journal of Process Control, Vol.72, 1-16, 2018
Global-nonlinear stochastic dynamics of a class of two-state two-parameter non-isothermal continuous stirred tank reactors
The global-nonlinear stochastic dynamics of a class of two-state two-parameter continuous exothermic chemical reactors subjected to noise disturbances is studied with Fokker-Planck's (FP's) partial differential equation (PDE) theory. The dependency of the stochastic on deterministic dynamics is formally established, and the fundamental characteristics of the associated two-state probability density function (PDF) are described in analytic form, including: (i) stationary state PDF, (ii) convection, diffusion, and metastability time scales along which the state PDF transient occurs, as well as (iii) conditions for PDF metastability. The correspondence between the determination of stochastic stationary state PEW and the assessment of deterministic multiplicity via Van Heerden's (VH) diagram is established. The developments and results are illustrated with numerical solution of FP's PDE, and put in perspective with typical and atypical results drawn with Monte Carlo (MC) method. (C) 2018 Elsevier Ltd. All rights reserved.
Keywords:Stochastic nonlinear reactor dynamics;Global deterministic reactor dynamics;Van Heerden diagram;Bifurcation;Structural stability;Fokker-Planck equation;State probability density function;Stochastic metastability