A solid polymer electrolyte (SPE) for calcium-ion conduction was produced and characterized. Poly(ethylene glycol) diacrylate was photocrosslinked under blue light in the presence of calcium salt to form a stable network with high thermal stability and promising conductivity. An ionic conductivity of 3.4 x 10(-4)S/cm at 110 degrees C and 3.0 x 10(-6) S/cm at room temperature was achieved, which is similar to early-stage lithium SPEs. The electrolytes evaluated under thermogravimetric analysis (TGA) remained stable up to temperatures of approximately 140 degrees C. XRD confirmed no salt precipitation within the polymer matrix, and Raman analysis indicated the complexation of the calcium ions to the PEGDA network. This study is a contribution towards suitable polymer electrolytes for solid-state calcium-ion batteries.