화학공학소재연구정보센터
Journal of Crystal Growth, Vol.511, 1-7, 2019
Effects of starting materials on the deposition behavior of hydrothermally synthesized {100}(c)-oriented epitaxial (K,Na)NbO3 thick films and their ferroelectric and piezoelectric properties
Epitaxial (K0.88Na0.12)NbO3 films were deposited at 240 degrees C onto (1 0 0)(c)SrRuO3//(1 0 0)SrTiO3 substrates utilizing a hydrothermal method. Both crystalline and amorphous niobium oxide powders were utilized as starting niobium sources with KOH and NaOH as potassium and sodium sources, respectively. Film thickness increased with deposition time, but eventually became saturated. The saturated film thickness of (K0.88Na0.12)NbO3 films prepared from the amorphous niobium source was greater than that from the crystalline source for mixtures of 6 and 7 mol/L KOH-NaOH solutions. This is found to be due to the suppression of the (K,Na)NbO3 powder simultaneously prepared with films by selecting amorphous niobium source. Their electrical and piezoelectric properties were nearly identical after following heat treatment at 600 degrees C for 10 min in an atmospheric O-2 flow irrespective of the starting niobium sources; The average values of remanent polarization and effective longitudinal piezoelectric constant, d(33), were 5-6 mu C/cm(2) and 45 pm/V, respectively.