The complexation of trivalent curium (Cm(III)) with chloride up to its respective saturation concentration is studied in dependency of the chloride-bearing electrolyte (LiCl, NaCl, MgCl2, CaCl2) in the temperature range of 25-200 degrees C by time-resolved laser fluorescence spectroscopy (TRLFS). At low chloride concentrations and temperatures the Cm(III) aquo ion dominates the species distribution. However, at both elevated chloride concentrations and temperatures speciation is dominated by CmCl2+(aq) and CmCl2+(aq), and significant molar fractions are even contributed by CmCl3 (aq) and CmCl4-(aq). Conditional stability constants log beta(n)'(t) are determined and extrapolated to the thermodynamic reference state using the specific ion-interaction theory (SIT). Modeling results in standard stability constants log beta(2)degrees(t) with slight deviation with respect to the valency of the electrolyte. As a result, an average value of log beta(2)degrees(25 degrees C) = (-1.16 +/- 0.10) is derived for the formation of CmCl2+. The complexation is found to be both endothermic as well as entropy driven with Delta H-r degrees = (60.5 +/- 1.5) kJ mol(-)(1), and Delta S-r degrees = (180.7 +/- 3.9) J mol(-)(1) K--(1). (C) 2018 Elsevier Ltd.