화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.132, 316-321, 2019
Standard enthalpies of formation of dicyclopropyldinitromethane and tricyclopropylmethane
The energies of combustion of liquid dicyclopropyldinitromethane and liquid tricyclopropylmethane were determined by calorimetry of combustion at T= 298.15 K. The enthalpies of vaporization were estimated on the basis of electrostatic potential model. The formation enthalpies of the compounds in liquid and gas states were obtained from these data. The gas enthalpies of formation were also calculated by methods of the group additivity and isodesmic reactions. The obtained experimental and calculation values were compared. (C) 2018 Elsevier Ltd.