화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.44, No.5, 3195-3207, 2019
Response of heat release to equivalence ratio variations in high Karlovitz premixed H-2/air flames at 20 atm
This paper presents three-dimensional direct numerical simulations of lean premixed H-2/air flames with equivalence ratios 0.4, 0.5 and 0.6, respectively. The initial Karlovitz number is around 2335 and the pressure is 20 atm, which is relevant to gas turbine conditions. The heat release in reaction zones under different equivalence ratios is examined statistically with the aim to extend our understanding of lean combustion under highpressure conditions. With increasing equivalence ratio, the relative thickness of reaction zone (delta(f)/delta(L)) is increasing for both laminar and turbulent flames, but the extent of increase is reduced under high equivalence ratio. By examining the local structures of flame fronts, it is found that trenches and plateaus of local equivalence ratio are located on separate sides of the reaction zone edge. Due to the decreased Lewis number under high equivalence ratio, the trench 'depth' and plateau 'height' are reduced. For the flame under ultra-lean conditions, there are some spots with temperatures above adiabatic temperature. This is attributed to the high-fraction of radicals in these regions, which will promote heat release. Furthermore, the heat release rates of elementary reactions are investigated with the analysis of radical fractions and rate constants. When the mixture equivalence ratio varies, the local heat release is changed in different temperature windows due to the combined effects of radical fractions and reaction rate constants. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.