화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.71, 465-480, March, 2019
DOI10.1016/j.jiec.2018.12.004  Export Citation
Dynamic adsorption.desorption of methyl ethyl ketone on MCM-41 and SBA-15 decorated with thermally activated polymers
Rafał Janus1, 2, †, Mariusz Wadrzyk1, 2, Piotr Natkanski3, Pegie Cool4, and Piotr Kustrowski3
  • 1AGH University of Science and Technology, Faculty of Energy and Fuels, al. A. Mickiewicza 30, 30-059 Krakow, Poland
  • 2AGH University of Science and Technology, AGH Centre of Energy, ul. Czarnowiejska 36, 30-054 Krakow, Poland
  • 3Faculty of Chemistry, Jagiellonian University, ul. Gronostajowa 2, 30-387 Kraków, Poland
  • 4Laboratory of Adsorption and Catalysis, Department of Chemistry, University of Antwerpen, Universiteitsplein 1, B-2610 Wilrijk, Belgium
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Three series of mesoporous adsorbents designed for removal of methyl ethyl ketone vapor (MEK) were synthesized: MCM-41 was decorated with various amounts of novolac resin (Nov) and polyacrylonitrile (PAN), while SBA-15 was modified with PAN. The composites were thermally activated towards an enhancement of MEK adsorption capacity and tested in a fixed bed adsorber. Structural features of parent silicas were investigated by XRD, while textural parameters of the composites were studied by low- temperature nitrogen adsorption. A surface composition was examined by DRIFT and XPS. It was found that decoration of the silica surface with small amounts of PAN improved the monolayer adsorption capacity. The MEK breakthrough curves and desorption profiles were employed for calculation of the monolayer capacity and total pore volume (VtotalMEK). The VtotalMEK for the materials with smaller pores (MCM-41) were comparable to those determined by nitrogen adsorption, whereas respective values for the solids with larger pores (SBA-15) were underestimated. The mechanism of adsorption of MEK onto the adsorbents was elucidated. The MEK molecules were adsorbed solely in the form of keto tautomer. The enhanced MEK adsorption capacity came from the beneficial textural features of the support and the presence of a ladder-type PAN structure containing O-groups.
Keywords:MCM-41;SBA-15;Novolac resin;Polyacrylonitrile;Volatile organic compounds;Dynamic adsorption
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