Anion exchange membrane prepared from imidazolium grafted poly (arylene ether ketone) with enhanced durability for vanadium redox flow battery

Yeonho Ahn; Dukjoon Kim

Journal of Industrial and Engineering Chemistry, Vol.71, 361-368, March, 2019

DOI10.1016/j.jiec.2018.11.047 Export Citation

Anion exchange membrane prepared from imidazolium grafted poly (arylene ether ketone) with enhanced durability for vanadium redox flow battery

Yeonho Ahn, and Dukjoon Kim^†

School of Chemical Engineering, Sungkyunkwan University, Suwon, Gyeonggi 16419, Republic of Korea

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The anion exchange membrane was synthesized from poly(arylene ether ketone) with 1-(3-aminopropyl) imidazole pendant groups (PAEK-API) for vanadium redox flow battery. The properties of the PAEK-API membranes were compared with those of Nafion® 117 membrane. All of the synthesized membranes showed higher ion exchange capacity but lower vanadium ion permeability than Nafion® 117 membrane. Also, the membranes showed excellent chemical stability in electrolyte solution. During the 100 cycling tests, the PAEK-API 2.0 membrane showed higher coulombic and energy efficiencies than Nafion® 117 membrane without any degradation.

Keywords:Anion exchange membrane;Durability;Imidazolium group;Vanadium ion permeability;Vanadium redox flow battery

[References]

Alotto P, Guarnieri M, Moro F, Renew. Sust. Energ. Rev., 29, 325 (2014)
Farhat AAM, Ugursal VI, Int. J. Energy Res., 34(15), 1309 (2010)
Suranovic S, Glob. Environ. Change, 23, 598 (2013)
McEvoy D, Gibbs DC, Longhurst JWS, Int. J. Energy Res., 24(3), 215 (2000)
Kiraly A, Pahor B, Kravanja Z, Energy, 55, 46 (2013)
Verwijs H, Eur. Energy Rev., 72 (2009).
Fri RW, Olson S, The National Academies Summit on America’s Energy Future, National Academies Press, 2008.
Kazacos M, Cheng M, Skyllas-Kazacos M, J. Appl. Electrochem., 20, 463 (1990)
Leung P, Li X, DeLeon CP, Berlouis L, Low CJ, Walsh FC, RscAdv., 2, 10125 (2012)
Skyllas-Kazacos M, Kasherman D, Hong D, Kazacos M, J. Power Sources, 35, 399 (1991)
Li JC, Zhang YP, Zhang S, Huang XD, J. Membr. Sci., 490, 179 (2015)
Parasuraman A, Lim TM, Menictas C, Skyllas-Kazacos M, Electrochim. Acta, 101, 27 (2013)
Si TK, Chowdhury K, Mukherjee M, Bera DC, Bhattacharyyaa R, J. Mol. Catal. A-Chem., 219(2), 241 (2004)
Kim S, Tighe TB, Schwenzer B, Yan JL, Zhang JL, Liu J, Yang ZG, Hickner MA, J. Appl. Electrochem., 41(10), 1201 (2011)
Nguyen MDT, Kim D, Solid State Ion., 270, 66 (2015)
Kang K, Kwon B, Choi SW, Lee J, Kim D, Int. J. Hydrog. Energy, 40(46), 16443 (2015)
Park J, Kim D, Int. J. Hydrog. Energy, 39(2), 1063 (2014)
Kim N, Kim D, Int. J. Hydrog. Energy, 34(19), 7919 (2009)
Choi SW, Luu DX, Le Mong A, Kwon B, Kim D, Solid State Ion., 279, 18 (2015)
Nguyen MDT, Yang S, Kim D, J. Power Sources, 328, 355 (2016)
Kang K, Kim D, J. Power Sources, 281, 146 (2015)
Han SY, Park J, Kim D, J. Power Sources, 243, 850 (2013)
Yang S, Ahn Y, Kim D, J. Mater. Chem. A, 5, 2261 (2017)
Kreuer KD, J. Membr. Sci., 185(1), 29 (2001)
Chen D, Hickner MA, Agar E, Kumbur EC, Electrochem. Commun., 26, 37 (2013)
Maurya S, Shin SH, Lee JY, Kim Y, Moon SH, RSC Adv., 6, 5198 (2016)
Gindt BP, Abebe DG, Tang ZJ, Lindsey MD, Chen J, Elgammal RA, Zawodzinski TA, Fujiwara T, J. Mater. Chem. A, 4
Lu D, Wen L, Nie F, Xue L, RSC Adv., 6, 6029 (2016)
Chen D, Hickner MA, Agar E, Kumbur EC, ACS Appl. Mater. Interfaces
Yun S, Parrondo J, Ramani V, Int. J. Hydrog. Energy, 41(25), 10766 (2016)
Yun S, Parrondo J, Ramani V, J. Mater. Chem. A, 2, 6605 (2014)

[Referenced By]

[1] Alotto P, Guarnieri M, Moro F, Renew. Sust. Energ. Rev., 29, 325 (2014)

[2] Farhat AAM, Ugursal VI, Int. J. Energy Res., 34(15), 1309 (2010)

[3] Suranovic S, Glob. Environ. Change, 23, 598 (2013)

[4] McEvoy D, Gibbs DC, Longhurst JWS, Int. J. Energy Res., 24(3), 215 (2000)

[5] Kiraly A, Pahor B, Kravanja Z, Energy, 55, 46 (2013)

[6] Verwijs H, Eur. Energy Rev., 72 (2009).

[7] Fri RW, Olson S, The National Academies Summit on America’s Energy Future, National Academies Press, 2008.

[8] Kazacos M, Cheng M, Skyllas-Kazacos M, J. Appl. Electrochem., 20, 463 (1990)

[9] Leung P, Li X, DeLeon CP, Berlouis L, Low CJ, Walsh FC, RscAdv., 2, 10125 (2012)

[10] Skyllas-Kazacos M, Kasherman D, Hong D, Kazacos M, J. Power Sources, 35, 399 (1991)

[11] Li JC, Zhang YP, Zhang S, Huang XD, J. Membr. Sci., 490, 179 (2015)

[12] Parasuraman A, Lim TM, Menictas C, Skyllas-Kazacos M, Electrochim. Acta, 101, 27 (2013)

[13] Si TK, Chowdhury K, Mukherjee M, Bera DC, Bhattacharyyaa R, J. Mol. Catal. A-Chem., 219(2), 241 (2004)

[14] Kim S, Tighe TB, Schwenzer B, Yan JL, Zhang JL, Liu J, Yang ZG, Hickner MA, J. Appl. Electrochem., 41(10), 1201 (2011)

[15] Nguyen MDT, Kim D, Solid State Ion., 270, 66 (2015)

[16] Kang K, Kwon B, Choi SW, Lee J, Kim D, Int. J. Hydrog. Energy, 40(46), 16443 (2015)

[17] Park J, Kim D, Int. J. Hydrog. Energy, 39(2), 1063 (2014)

[18] Kim N, Kim D, Int. J. Hydrog. Energy, 34(19), 7919 (2009)

[19] Choi SW, Luu DX, Le Mong A, Kwon B, Kim D, Solid State Ion., 279, 18 (2015)

[20] Nguyen MDT, Yang S, Kim D, J. Power Sources, 328, 355 (2016)

[21] Kang K, Kim D, J. Power Sources, 281, 146 (2015)

[22] Han SY, Park J, Kim D, J. Power Sources, 243, 850 (2013)

[23] Yang S, Ahn Y, Kim D, J. Mater. Chem. A, 5, 2261 (2017)

[24] Kreuer KD, J. Membr. Sci., 185(1), 29 (2001)

[25] Chen D, Hickner MA, Agar E, Kumbur EC, Electrochem. Commun., 26, 37 (2013)

[26] Maurya S, Shin SH, Lee JY, Kim Y, Moon SH, RSC Adv., 6, 5198 (2016)

[27] Gindt BP, Abebe DG, Tang ZJ, Lindsey MD, Chen J, Elgammal RA, Zawodzinski TA, Fujiwara T, J. Mater. Chem. A, 4

[28] Lu D, Wen L, Nie F, Xue L, RSC Adv., 6, 6029 (2016)

[29] Chen D, Hickner MA, Agar E, Kumbur EC, ACS Appl. Mater. Interfaces

[30] Yun S, Parrondo J, Ramani V, Int. J. Hydrog. Energy, 41(25), 10766 (2016)

[31] Yun S, Parrondo J, Ramani V, J. Mater. Chem. A, 2, 6605 (2014)