화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.27, No.1, 96-104, January, 2019
DOI10.1007/s13233-019-7032-5  Export Citation
Synthesis and Properties of Self-healing Metallopolymers with 5-Vinyltetrazole Units and Zn(II)
Mifa Chen1, 2, Wenxiang Wang1, 2, Hou Chen1, 2, †, Liangjiu Bai1, 2, †, Zhongxin Xue1, 2, Donglei Wei1, 2, Huawei Yang1, 2, and Yuzhong Niu1, 2
  • 1School of Chemistry and Materials Science, Key Laboratory of High Performance and Functional Polymer in the Universities of Shandong Province, Ludong University, Yantai 264025, P. R. China
  • 2Collaborative Innovation Center of Shandong Province for High Performance Fibers and Their Composites, Ludong University, Yantai 264025, P. R. China
E-mail:,
The development of reversible and efficient self-healing materials symbolizes an emerging and challenging task in intelligent materials science. In this paper, a facile one-pot and two-step methodology was developed for the preparation of polyacrylonitrile-r-poly(butyl acrylate) (PAN-r-PnBA) and its subsequent modification. Zinc chloride (ZnCl2) was used as a catalyst to modify cyano groups and generate tetrazole groups of PAN-r-PnBA. Simultaneously, ZnCl2 effectively coordinates with the generated tetrazole group for highly self-healing performance. It was demonstrated that the metallopolymers (MPs) exhibited excellent self-healing properties at ambient temperature. The prepared tetrazole-based MPs can be used as a wide range of self-healing materials.
Keywords:self-healing;polyacrylonitrile;metallopolymers
  1. Hager MD, Greil P, Leyens C, van der Zwaag S, Schubert US, Self-Healing Mater. Adv. Mater., 22, 5424 (2010)
  2. Boncheva M, Whitesides GM, Angew. Chem.-Int. Edit., 42, 2644 (2003)
  3. Zhang Q, Liu LB, Pan CG, Li D, J. Mater. Sci., 53(1), 27 (2018)
  4. Ryu YS, Oh KW, Kim SH, Macromol. Res., 24(10), 874 (2016)
  5. Ullah H, Azizli KAM, Man ZB, Ismail MBC, Khan MI, Polym. Rev., 56, 429 (2016)
  6. Thakur VK, Kessler MR, Polymer, 69, 369 (2015)
  7. Liu X, Lee JK, Kessler MR, Macromol. Res., 19(10), 1056 (2011)
  8. Guimard NK, Oehlenschlaeger KK, Zhou J, Hilf S, Schmidt FG, Barner-Kowollik C, Macromol. Chem. Phys., 213, 131 (2012)
  9. Hu L, Cheng XJ, Zhang AQ, J. Mater. Sci., 50(5), 2239 (2015)
  10. Fifo O, Ryan K, Basu B, Smart Mater. Struct., 23, 095017 (2014)
  11. Lee JK, Hong SJ, Liu X, Yoon SH, Macromol. Res., 12(5), 478 (2004)
  12. Caruso MM, Blaiszik BJ, Jin H, Schelkopf SR, Stradley DS, Sottos NR, White SR, Moore JS, ACS Appl. Mater. Interfaces, 2, 1195 (2010)
  13. Zhang G, Zhao Q, Yang L, Zou W, Xi X, Xie T, ACS Macro Lett., 5, 805 (2016)
  14. Lee HY, Cha SH, Macromol. Res., 25(6), 640 (2017)
  15. Ling L, Li J, Zhang G, Sun R, Wong CP, Macromol. Res., 26(4), 365 (2018)
  16. Canadell J, Goossens H, Klumperman B, Macromolecules, 44(8), 2536 (2011)
  17. Herbst F, Dohler D, Michael P, Binder WH, Macromol. Rapid Commun., 34(3), 203 (2013)
  18. Shi Y, Wang M, Ma C, Wang Y, Li X, Yu G, Nano Lett., 15, 6276 (2015)
  19. Yang B, Zhang H, Peng H, Xu Y, Wu B, Weng W, Li L, Polym. Chem., 5, 1945 (2014)
  20. Hart KR, Sottos NR, White SR, Polymer, 67, 174 (2015)
  21. Mei JF, Jia XY, Lai JC, Sun Y, Li CH, Wu JH, Cao Y, You XZ, Bao ZN, Macromol. Rapid Commun., 37(20), 1667 (2016)
  22. Bode S, Zedler L, Schacher FH, Dietzek B, Schmitt M, Popp J, Hager MD, Schubert US, Adv. Mater., 25(11), 1634 (2013)
  23. Burnworth M, Tang LM, Kumpfer JR, Duncan AJ, Beyer FL, Fiore GL, Rowan SJ, Weder C, Nature, 472(7343), 334 (2011)
  24. Mozhdehi D, Ayala S, Cromwell OR, Guan ZB, J. Am. Chem. Soc., 136(46), 16128 (2014)
  25. Bergman SD, Wudl F, J. Mater. Chem., 18, 41 (2008)
  26. Sandmann B, Happ B, Kupfer S, Schacher FH, Hager MD, Schubert US, Macromol. Rapid Commun., 36(7), 604 (2015)
  27. Pu HT, Wu J, Wan DC, Chang ZH, J. Membr. Sci., 322(2), 392 (2008)
  28. Tsarevsky NV, Bernaerts KV, Dufour B, Du Prez FE, Matyjaszewski K, Macromolecules, 37(25), 9308 (2004)
  29. Aromi G, Barrios LA, Roubeau O, Gamez P, Coord. Chem. Rev., 255, 485 (2011)
  30. Zeng JR, Cheng CC, Chang CJ, Huang CH, Chen JK, Dyes Pigment., 139, 300 (2017)
  31. Lee H, Jung SH, Han WS, Moon JH, Kang S, Lee JY, Jung JH, Shinkai S, Chem. A: Eur. J., 17, 2823 (2011)
  32. Wang WX, Chen MF, Niu YZ, Tao Q, Bai LJ, Chen HP, Cheng Z, RSC Adv., 7, 47316 (2017)
  33. Liu X, Chen H, Wang CH, Qu RJ, Ji CN, Sun CM, Zhang Y, J. Hazard. Mater., 175(1-3), 1014 (2010)
  34. Zong GX, Chen H, Qu RJ, Wang CH, Ji NY, J. Hazard. Mater., 186(1), 614 (2011)
  35. Qu RJ, Zhang Y, Qu WW, Sun CM, Chen J, Ping Y, Chen H, Niu YZ, Chem. Eng. J., 219, 51 (2013)
  36. Majeed S, Fierro D, Buhr K, Wind J, Du B, Boschetti-De-Fierro A, Abetz V, J. Membr. Sci., 403, 101 (2012)
  37. Chien AT, Liu HC, Newcomb BA, Xiang C, Tour JM, Kumar S, ACS Appl. Mater. Interfaces, 7, 5281 (2015)
  38. Zhang LF, Aboagye A, Kelkar A, Lai CL, Fong H, J. Mater. Sci., 49(2), 463 (2014)
  39. Krentsel LB, Kudryavtsev YV, Rebrov AI, Litmanovich AD, Plate NA, Macromolecules, 34(16), 5607 (2001)
  40. Aksoy OE, Ates B, Cerkez I, J. Mater. Sci., 52(17), 10013 (2017)
  41. Bai LJ, Wang DJ, Chen H, Li DX, Xu YY, Yu LL, Wang WX, Polym. Bull., 72(10), 2455 (2015)
  42. Feng Q, Wang Q, Tang B, Wei A, Wang X, Wei Q, Huang F, Cai Y, Hou D, Bi S, Polym. Int., 62, 251 (2013)
  43. Xu YY, Hao ZH, Chen H, Sun JM, Wang DJ, Ind. Eng. Chem. Res., 53(12), 4871 (2014)
  44. Voggu R, Suguna P, Chandrasekaran S, Rao CNR, Chem. Phys. Lett., 443(1-3), 118 (2007)
  45. Gliscinska E, Gutarowska B, Brycki B, Krucinska I, J. Appl. Polym. Sci., 128(1), 767 (2013)
  46. Kamble RR, Biradar DB, Meti GY, Taj T, Gireesh T, Khazi IAM, Vaidyanathan ST, Mohandoss R, Sridhar B, Parthasarathi B, J. Chem. Sci., 123, 393 (2011)
  47. Mancheno OG, Bistri O, Bolm C, Org. Lett., 9, 3809 (2007)
  48. Nasrollahzadeh M, Bayat Y, Habibi D, Moshaee S, Tetrahedron Lett., 50, 4435 (2009)
  49. Chen GQ, Xu ZJ, Liu Y, Zhou CY, Che CM, Synlett, 8, 1174 (2011)
  50. Van Oss CJ, Chaudhury MK, Good RJ, Sep. Sci. Technol., 22, 1515 (1987)
  51. Zhu DD, Ye Q, Lu XM, Lu QH, Polym. Chem., 6, 5086 (2015)
  52. Gu Z, Li SH, Zhang FL, Wang ST, Adv. Sci., 3, 150032 (2016)
  53. Zeng HB, Huang J, Tian Y, Li L, Tirrell MV, Israelachvili JN, Macromolecules, 49(14), 5223 (2016)
  54. Faghihnejad A, Feldman KE, Yu J, Tirrell MV, Israelachvili JN, Hawker CJ, Kramer EJ, Zeng HB, Adv. Funct. Mater., 24(16), 2322 (2014)
  55. van Oss CJ, Chaudhury M, Good RJ, Adv. Colloid Interface Sci., 28, 35 (1987)
  56. Krogsgaard M, Hansen MR, Birkedal H, J. Mater. Chem. B, 2, 8292 (2014)
  57. Niu YZ, Qu RJ, Chen H, Mu L, Liu XG, Wang T, Zhang Y, Sun CM, J. Hazard. Mater., 278, 267 (2014)
  58. Niu YZ, Qu RJ, Sun CM, Wang CH, Chen H, Ji CN, Zhang Y, Shao X, Bu FL, J. Hazard. Mater., 244, 276 (2013)
  59. Chen H, Liang Y, Wang ML, Lv PL, Xuan YH, Chem. Eng. J., 147(2-3), 297 (2009)
  60. Zhang SX, Zhang YY, Liu JS, Xu Q, Xiao HQ, Wang XY, Xu H, Zhou J, Chem. Eng. J., 226, 30 (2013)
  61. Liu Y, Xu L, Liu JS, Liu XY, Chen CH, Li GY, Meng YF, Chem. Eng. J., 285, 698 (2016)
  62. Schmidt S, Reinecke A, Wojcik F, Pussak D, Hartmann L, Harrington MJ, Biomacromolecules, 15(5), 1644 (2014)
  63. Hong GN, Zhang H, Lin YJ, Chen YJ, Xu YZ, Weng WG, Xia HP, Macromolecules, 46(21), 8649 (2013)
  64. Maret W, Li Y, Chem. Rev., 109(10), 4682 (2009)