The optimal conditions of the aluminum electrochemical anodization and electrochemical and chemical metallization were determined. Metallized nanoporous anodic alumina (NAA) films with ultrahigh/average/low density of pores were obtained using the optimal conditions. The physical and chemical properties of the obtained NAA films were studied by high-resolution scanning electron microscopy and the reflective interference spectra in a wavelength range of 235-735 nm. Possible applications of the obtained NAA films are in micro/nanoscale lasers with indirect electrical pumping by laser diodes; optical interferometric chemical nanosensors; and the selective interference coloration and protection of the metal surface.