화학공학소재연구정보센터
Korean Journal of Materials Research, Vol.28, No.11, 653-658, November, 2018
W-1.5 ZrO2 복합재료 합성과 급속소결
Synthesis and Rapid Consolidation of W-1.5 ZrO2 Composite
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ZrO2 is a candidate material for hip and knee joint replacements because of its excellent combination of biocompatibility, corrosion resistance and low density. However, the drawback of pure ZrO2 is a low fracture toughness at room temperature. One of the most obvious tactics to cope with this problem is to fabricate a nanostructured composite material. Nanomaterials can be produced with improved mechanical properties(hardness and fracture toughness). The high-frequency induction heated sintering method takes advantage of simultaneously applying induced current and mechanical pressure during sintering. As a result, nanostructured materials can be achieved within very short time. In this study, W and ZrO2 nanopowders are mechanochemically synthesized from WO3 and Zr powders according to the reaction(WO3 + 3/2 Zr→W+ 3/2 ZrO2). The milled powders are then sintered using high-frequency induction heating within two minutes under the uniaxial pressure of 80MPa. The average fracture toughness and hardness of the nanostructured W-3/2 ZrO2 composite sintered at 1300oC are 540 kg/mm2 and 5 MPa·m1/2, respectively. The fracture toughness of the composite is higher than that of monolithic ZrO2. The phase and microstructure of the composite is also investigated by XRD and FE-SEM.
  1. Kwak SM, Park HK, Shon IJ, Korean J. Met. Mater., 51, 341 (2013)
  2. Shon IJ, Yoon JK, Hong KT, Met. Mater. Int., 24, 130 (2018)
  3. Shon IJ, Int. J. Refract. Met. Hard Mater., 72, 257 (2018)
  4. Shon IJ, Ceram. Int., 44, 2587 (2018)
  5. Shon IJ, Korean J. Met. Mater., 51, 110 (2017)
  6. Shon IJ, Ceram. Int., 43, 1612 (2017)
  7. Shon IJ, Yoon JK, Hong KT, Korean J. Met. Mater., 55, 179 (2017)
  8. Shon IJ, Int. J. Refract. Met. Hard Mater., 64, 242 (2017)
  9. Shon IJ, Ceram. Int., 43, 890 (2017)
  10. Coble RL, J. Appl. Phys., 41, 4798 (1970)
  11. Shen ZJ, Johnsson M, Zhao Z, Nygren M, J. Am. Ceram. Soc., 85(8), 1921 (2002)
  12. Garay JE, Anselmi-Tamburini U, Munir ZA, Glade SC, Asoka-Kumar P, Appl. Phys. Lett., 85, 573 (2004)
  13. Garay JE, Anselmi-Tamburini U, Munir ZA, Acta Mater., 51, 4487 (2003)
  14. Kwon SM, Lee SJ, Shon IJ, Ceram. Int., 41, 835 (2015)
  15. Suryanarayana C, Norton MG, X-ray diffraction: A practical approach, p. 213, Plenum Press, New York, (1998).
  16. Niihara K, Morena R, Hasselman DPH, J. Mater. Sci. Lett., 1, 13 (1982)
  17. Malewar R, Kumar KS, Murty BS, Sarma B, Pabi SK, J. Mater. Res., 22, 1200 (2007)