화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.35, No.12, 2384-2393, December, 2018
DOI10.1007/s11814-018-0181-y  Export Citation
Hydrogels with diffusion-facilitated porous network for improved adsorption performance
Yan-yan Pei, Dong-mei Guo, Qing-da An†, Zuo-yi Xiao, Shang-ru Zhai†, and Bin Zhai
  • Faculty of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China
E-mail:,
Porous alginate-based hydrogel beads (porous ABH) have been prepared through a facile and sustainable template-assisted method using nano-calcium carbonate and nano-CaCO3 as pore-directing agent for the efficient capture of methylene blue (MB). The materials were characterized by various techniques. The sorption capacities of ABH towards MB were compared with pure sodium alginate (ABH-1:0) in batch and fixed-bed column adsorption studies. The obtained adsorbent (ABH-1:3) has a higher BET surface area and a smaller average pore diameter. The maximum adsorption capacity of ABH-1:3 obtained from Langmuir model was as high as 1,426.0mg g?1. The kinetics strictly followed pseudo-second order rate equation and the adsorption reaction was effectively facilitated, approximately 50minutes to achieve adsorption equilibrium, which was significantly shorter than that of ABH-1:0. The thermodynamic parameters revealed that the adsorption was spontaneous and exothermic. Thomas model fitted well with the breakthrough curves and could describe the dynamic behavior of the column. More significantly, the uptake capacity of ABH-1:3 was still higher than 75% of the maximum adsorption capacity even after ten cycles, indicating that this novel adsorbent can be a promising adsorptive material for removal of MB from aqueous solution under batch and continuous systems.
Keywords:Porous Structures;Hydrogel Beads;Nano-CaCO3;Dye;Adsorption
  1. Gusmao KAG, Gurgel LVA, Melo TMS, Gil LF, Dyes Pigment., 92, 967 (2012)
  2. Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater., 177(1-3), 70 (2010)
  3. Metivier-Pignon H, Faur-Brasquet C, Le Cloirec P, Sep. Purif. Technol., 31(1), 3 (2003)
  4. Tu H, Yu Y, Chen JJ, Shi XW, Zhou JL, Deng HB, Du YM, Polym. Chem., 8, 2913 (2017)
  5. Ma DZ, Zhu BD, Cao B, Wang J, Zhang JW, Appl. Surf. Sci., 422, 944 (2017)
  6. Lin JY, Tang CYY, Ye WY, Sun SP, Hamdan SH, Volodin A, Van Haesendonck C, Sotto A, Luis P, Van der Bruggen B, J. Membr. Sci., 493, 690 (2015)
  7. Chong MN, Jin B, Chow CWK, Saint C, Water Res., 44, 2997 (2010)
  8. Franca RDG, Vieira A, Mata AMT, Carvalho GS, Pinheiro HM, Lourenco ND, Water Res., 85, 327 (2015)
  9. Wu ZB, Zhong H, Yuan XZ, Wang H, Wang LL, Chen XH, Zeng GM, Wu Y, Water Res., 67, 330 (2014)
  10. Seyahmazegi EN, Mohammad-Rezaei R, Razmi H, Chem. Eng. Res. Des., 109, 824 (2016)
  11. Wong KT, Eu NC, Ibrahim S, Kim H, Yoon Y, Jang M, J. Clean Prod., 115, 337 (2016)
  12. Almeida CAP, Debacher NA, Downs AJ, Cottet L, Mello CAD, J. Colloid Interface Sci., 332(1), 46 (2009)
  13. Song KL, Xu HL, Xu L, Xie KL, Yang YQ, Bioresour. Technol., 232, 254 (2017)
  14. Lv JL, Zhai SR, Fan Y, Lei ZM, An QD, J. Taiwan Chem. Eng., 62, 209 (2016)
  15. Zhang H, Chen L, Li LF, Yang YZ, Liu XG, J. Porous Mat., 24, 341 (2017)
  16. Rehman HU, Aman A, Nawaz MA, Karim A, Ghani M, Baloch AH, Qader SAU, Int. J. Biol. Macromol., 82, 127 (2016)
  17. Zong YL, Zhang YD, Lin XY, Ye D, Qiao D, Zeng SN, RSC Adv., 7, 31352 (2017)
  18. Wu DB, Zhang L, Wang L, Zhu BH, Fan LY, J. Chem. Technol. Biotechnol., 86(3), 345 (2011)
  19. Sikorski P, Mo F, Skjak-Braek G, Stokke BT, Biomacromolecules, 8(7), 2098 (2007)
  20. Zhuang Y, Yu F, Chen JH, Ma J, J. Environ. Chem. Eng., 4, 147 (2016)
  21. Mohammed N, Grishkewich N, Waeijen HA, Berry RM, Tam KC, Carbohydr. Polym., 136, 1194 (2016)
  22. Benhouria A, Islam MA, Zaghouane-Boudiaf H, Boutahala M, Hameed BH, Chem. Eng. J., 270, 621 (2015)
  23. Hassan AF, Abdel-Mohsen AM, Fouda MMG, Carbohydr. Polym., 102, 192 (2014)
  24. Mohammed N, Grishkewich N, Berry RM, Tam KC, Cellulose, 22, 3725 (2015)
  25. Sun LB, Li AG, Liu XD, Liu XQ, Feng DW, Lu WG, Yuan DQ, Zhou HC, J. Mater. Chem. A, 3, 3252 (2015)
  26. Platero E, Fernandez ME, Bonelli PR, Cukierman AL, J. Colloid Interface Sci., 491, 1 (2017)
  27. Huang Q, Liu MY, Zhao J, Chen JY, Zeng GJ, Huang HY, Tian JW, Wen YQ, Zhang XY, Wei Y, Appl. Surf. Sci., 427, 535 (2018)
  28. Liang XT, Fan XY, Li RM, Li SR, Shen SK, Hu DD, Bioresour. Technol., 250, 178 (2018)
  29. Ataei-Germi T, Nematollahzadeh A, J. Colloid Interface Sci., 470, 172 (2016)
  30. Shan D, Zhu MJ, Xue HG, Cosnier S, Biosens. Bioelectron., 22, 1612 (2007)
  31. Li LB, Fang YP, Vreeker R, Appelqvist I, Biomacromolecules, 8(2), 464 (2007)
  32. Jin LN, Zhao XS, Qian XY, Dong MD, J. Colloid Interface Sci., 509, 245 (2018)
  33. Macedo JD, da Costa NB, Almeida LE, Vieira EFD, Cestari AR, Gimenez ID, Carreno NLV, Barreto LS, J. Colloid Interface Sci., 298(2), 515 (2006)
  34. Diaz-Teran J, Nevskaia DM, Fierro JL, Lopez-Peinado AJ, Jerez A, Microporous Mesoporous Mater., 60, 173 (2003)
  35. Chen XG, Park HJ, Carbohydr. Polym., 53, 355 (2003)
  36. Agulhon P, Markova V, Robitzer M, Quignard F, Mineva T, Biomacromolecules, 13(6), 1899 (2012)
  37. Lu T, Xiang T, Huang XL, Li C, Zhao WF, Zhang Q, Zhao CS, Carbohydr. Polym., 133, 587 (2015)
  38. Luo P, Zhang B, Zhao Y, Wang J, Zhang H, Liu J, Korean J. Chem. Eng., 28(3), 800 (2011)
  39. Zhang CZ, Su JJ, Zhu HX, Xiong JH, Liu XL, Li DX, Chen YM, Li YH, RSC Adv., 7, 34182 (2017)
  40. Zhu ZG, Wu P, Liu GJ, He XF, Qi BY, Zeng GF, Wang W, Sun YH, Cui FY, Chem. Eng. J., 313, 957 (2017)
  41. Rocher V, Bee A, Siaugue JM, Cabuil V, J. Hazard. Mater., 178(1-3), 434 (2010)
  42. Liu L, Wan YZ, Xie YD, Zhai R, Zhang B, Liu JD, Chem. Eng. J., 187, 210 (2012)
  43. Belhouchat N, Zaghouane-Boudiaf H, Viseras C, Appl. Clay Sci., 135, 9 (2017)
  44. Salisu A, Sanagi MM, Naim AA, Karim KJ, Der Pharma Chemica, 7, 237 (2015)
  45. Oladipo AA, Gazi M, J. Water Process Eng., 2, 43 (2014)
  46. Li Q, Tang X, Sun YY, Wang YF, Long YC, Jiang J, Xu H, RSC Adv., 5, 25337 (2015)
  47. Liu Y, Zhong GX, Liu ZC, Meng MJ, Jiang YH, Ni L, Guo WL, Liu FF, RSC Adv., 5, 85691 (2015)
  48. Vijayaraghavan K, Jegan J, Palanivelu K, Velan M, Sep. Purif. Technol., 44(1), 53 (2005)