It is a huge challenge to design and develope a highly active and stable non-noble metal electrocatalyst for hydrogen evolution reaction (HER) in alkaline solution. Increasing the active sites and improving conductivity of catalysts are the effective ways to enhance the catalytic performance. Here, nanoparticle-stacked porous NiCoO2@C microflakes arrays grown on Ni foam (NiCoO2@C-NF) was synthesized through a simple high temperature heat treatment reaction of the corresponding NiCo2O4-NF. The nanoparticle-stacked porous microflakes arrays provide a large amount of exposed active sites. Thus, NiCoO2@C-NF with 0.072 g of glucose used for their preparation exhibits remarkable performance with -10 and -100mA cm(-2) for HER at overpotentials of -128 and -184mV in 1.0M NaOH solution, respectively. It is much better than that of NiCo2O4-NF (a eta(10) of -221mV and eta(100) of -379 mV). (C) 2018 Elsevier Ltd. All rights reserved.