The reunion of Sn is always a troublesome issue when it's used as the energy storage materials, on the one hand it comes from the preparation process due to its low melting point, and on the other hand it comes from the Li-Sn alloying process because of its natural tendency of migration. The Sn/SnO2/spherical graphene composite prepared by one-step low temperature hydrothermal reduction method can effectively solve this problem. In the composite, Sn/SnO2 tiny nanoparticles with average diameter of 5 nm distribute evenly between multilayers of graphene sheets presenting a hollow spherical structure. The introduction of SnO2 can effectively restrain the agglomeration of Sn nanoparticles during alloying process since an amorphous Li2O matrix is formed to separate the adjacent active particles. The sandwich graphene hollow sphere skeleton effectively buffers the volume expansion of Sn/SnO2 and further restricts their migration and agglomeration. Due to the above advantages, the nano-Li2O generating from the decomposition of SnO2 can contact closely with excessive nano-Sn in restricted area, promoting facile conversed conversion reaction. Therefore, the composite exhibits high reversible capacity and excellent cycle performance. A stable and high specific capacity of 843.8 mAh g(-1) is obtained after 100 cycles at 0.1 C. (C) 2018 Elsevier Ltd. All rights reserved.