화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 364-371, December, 2018
DOI10.1016/j.jiec.2018.08.009  Export Citation
Polymerization of aniline using a peroxidase-mimetic catalyst
Min-Chul Kim, Youngjoon Lim, and Sang-Yup Lee†
  • Department of Chemical and Biomolecular Engineering, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749, Republic of Korea
E-mail:
Enzyme polymerization is a benign process exploiting the unique activity of enzymes. In this study, a peroxidase-mimetic catalyst is demonstrated as an alternative to horseradish peroxidase (HRP) for the polymerization of aniline. The mimetic catalyst successfully catalyzes the polymerization of aniline monomers to produce polyaniline (PANI) in an aqueous solution. The PANI produced is rich of para-structure that is generally observed when HRP is used as a catalyst. Compared to HRP, the peroxidase-mimetic catalyst shows a considerably higher catalytic activity at neutral and weak basic conditions (pH >6.5) and at temperatures over 45 °C, at which HRP is denatured.
Keywords:Enzyme polymerization;Polyaniline;Peroxidase;Histidine;Catalyst
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