화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 335-341, December, 2018
DOI10.1016/j.jiec.2018.08.004  Export Citation
Catalytic effect of metal oxides on CO2 absorption in an aqueous potassium salt of lysine
Sivanesan Dharmalingam, Ki Tae Park, Ju-Yeol Lee1, Il-Gun Park2, and Soon Kwan Jeong†
  • Greenhouse Gas Laboratory, Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, Daejeon 34129, Republic of Korea
  • 1ANYTECH Co., Ltd., 88, Sinwon-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, Republic of Korea
  • 2PYUNGHWA Engineering Consultants Ltd., 415, Heungan-dearo, Dongan-gu, Anyang-si, Gyeonggi-do, 14059, Republic of Korea
E-mail:
We report the catalytic effects of metal oxides on the CO2 absorption rate in an aqueous potassium salt of l-lysine-HCl using the vapor liquid equilibrium method. The best CO2 absorption rate obtained through testing metal oxides in a highly concentrated potassium salt of amino acids (2.0 M) was identified using CuO. The recyclability of the metal oxides was tested over three cycles. The catalyst CuO was found to enhance the absorption rate of CO2 by 61%. A possible mechanism was proposed based on NMR spectroscopy studies. Further, the effect of change in liquid absorbent viscosity on CO2 absorption is discussed.
Keywords:CO2 absorption;Catalytic effect;Metal Oxides;Aqueous amino acid salt;L-Lysine potassium salt;Mechanistic studies
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