화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.68, 257-266, December, 2018
Ultrathin graphene-like 2D porous carbon nanosheets and its excellent capacitance retention for supercapacitor
E-mail:
Here, a controlled green synthesis route involving hydrothermal pre-carbonization cum pyrolysis is reported that converts cucumber into graphene-like carbon nanosheets for supercapacitor application. Transmission electron microscopy analysis reveals the formation of ultra-thin carbon nanosheets with distributed pores. This cucumber derived carbon exhibits high specific capacitance of 143 F g-1 in aqueous electrolyte. The two-electrode symmetric cell exhibits a specific capacitance of 58 F g-1 at high current density, and high capacitance retention of 97% after 1000 cycles. This simple low-cost process involving widely available cucumber as biomass precursor is a promising, commercially viable approach for developing high-performance supercapacitors.
  1. Lukatskaya MR, Dunn B, Gogotsi Y, Nat. Commun., 7, 12647 (2016)
  2. Li B, Gu P, Feng Y, Zheng G, Huang K, Xue H, Pang H, Adv. Funct. Mater., 27, 160578 (2017)
  3. Xu Y, Zheng S, Tang H, Guo X, Xue H, Pang H, Energy Storage Mater., 9, 11 (2017)
  4. Zheng S, Li X, Yan B, Hu Q, Xu Y, Xiao X, Xue H, Pang H, Adv. Energy Mater., 7, 160273 (2017)
  5. Xu Y, Li B, Zheng S, Wu P, Zhan J, Xue H, Xu Q, Pang H, J. Mater. Chem. A (2018), doi:http://dx.doi.org/10.1039/C8TA03128B.
  6. Li Q, Zheng S, Xu Y, Xue H, Pang H, Chem. Eng. J., 33, 505 (2018)
  7. Kiamahalleh MV, Zein SHS, Najafpour G, Sata SA, Buniran S, Nano, 7, 1 (2012)
  8. Upare DP, Yoon S, Lee CW, Korean J. Chem. Eng., 28(3), 731 (2011)
  9. Frackowiak E, Beguin F, Carbon, 39, 937 (2001)
  10. Cooney DO, Activated Charcoal: Antidotal and Other Medical Uses, New York, USA, 1980.
  11. Han Y, Dong XT, Zhang C, Liu SX, J. Power Sources, 211, 92 (2012)
  12. Chen M, Kang X, Wumaier T, Dou J, Gao B, Han Y, Xu G, Liu Z, Zhang L, J. Solid State Electrochem., 17, 1005 (2013)
  13. Biswal M, Banerjee A, Deo M, Ogale S, Energy Environ. Sci., 6, 1249 (2013)
  14. Qian W, Sun F, Xu Y, Qiu L, Liu C, Wang S, Yan F, Energy Environ. Sci., 7, 379 (2014)
  15. Gao F, Qu J, Zhao Z, Wang Z, Qiu J, J. Electrochim. Acta., 190, 1134 (2016)
  16. Wang H, Li Z, Jin KT, Holt CMB, Tan X, Xu Z, Amirkhiz BS, Harfield D, Anyia A, Stephenson T, Mitlin D, Carbon, 57, 317 (2013)
  17. Li Z, Zhang L, Amirkhiz BS, Tan X, Xu Z, Wang H, Olsen BC, Holt CMB, Miltin D, Adv. Energy Mater., 2, 431 (2012)
  18. Simon P, Gogotsi Y, Nat. Mater., 7(11), 845 (2008)
  19. White RJ, Budarin V, Luque R, Clark JH, Macquarrie DJ, Chem. Soc. Rev., 38, 3401 (2009)
  20. Fang Y, Gu D, Zou Y, Wu Z, Li F, Che R, Deng Y, Tu B, Zhao D, Angew. Chem.-Int. Edit., 49, 7987 (2010)
  21. Zhao L, Chen XF, Wang XC, Zhang YJ, Wei W, Sun YH, Antonietti M, Titirici MM, Adv. Mater., 22(30), 3317 (2010)
  22. Wang LL, Guo YP, Zou B, Rong CG, Ma XY, Qu YN, Li Y, Wang ZC, Bioresour. Technol., 102(2), 1947 (2011)
  23. Paraknowitsch JP, Thomas A, Antonietti M, Chem. Mater., 21, 1170 (2009)
  24. White RJ, Tauer K, Antonietti M, Titirici MM, J. Am. Chem. Soc., 132, 17360 (2011)
  25. Selvi BR, Jagadeesan D, Suma BS, Nagashankar G, Arif M, Eswaramoor-thy M, Balasubramanyam K, Kundu TK, Nano Lett., 8, 3182 (2008)
  26. “2012 Agricultural Statistics Annual.” United States Department of Agriculture National Agricultural Statistics Service. USDA, 23 Oct. 2015. Web. 02 Dec. 2015.
  27. Belitz HD, Grosch W, Chemistry of Food, Ed. Acribia S.A., Zaragoza, p.825 1997.
  28. Zhou D, Wang H, Mao N, Chen Y, Zhou Y, Yin T, Xie H, Liu W, Chen S, Wang X, Microporous Mesoporous Mater., 241, 202 (2017)
  29. Cao Y, Zhang Z, Long J, Liang J, Lin H, Lin H, Wang X, J. Mater. Chem. A, 2, 17797 (2014)
  30. Mhamane D, Ramadan W, Fawzy M, Rana A, Dubey M, Rode C, Lefez B, Hannoyerd B, Ogale S, Green Chem., 13, 1990 (2011)
  31. Shimada T, Sugai T, Fantini C, Souza M, Cancado LG, Jorio A, Pimenta MA, et al., Carbon, 43, 1049 (2005)
  32. Sun X, Li Y, Angew. Chem.-Int. Edit., 23, 597 (2004)
  33. Xu T, Song J, Gordin ML, Sohn H, Yu Z, Chen S, Wang D, ACS Appl. Mater. Interfaces, 5, 11355 (2013)
  34. Yuan K, Guo-Wang P, Hu T, Shi L, Zeng,R Forster M, Pichler T, Chen Y, Scherf U, Chem. Mater., 27, 7403 (2015)
  35. Plaksin GV, Baklanova ON, Duplyakin VK, Drozdov VA, in: Progress in Thermochemical Biomass Conversion, Blackwell Science Ltd, Oxford, UK, 2001.
  36. Zhao Y, Hu LF, Zhao SY, Wu LM, Adv. Funct. Mater., 26(23), 4085 (2016)
  37. Xu L, Zhao Y, Lian JB, Xu YG, Bao J, Qiu JX, Xu L, Xu H, Hua MQ, Li HM, Energy, 123, 296 (2017)
  38. Zhao Y, Xu L, Huang S, Bao J, Qiu J, Lian J, Xu L, Huang Y, Xu Y, Li H, J. Alloy. Compd., 702, 178 (2017)
  39. Zhao Y, Xu Y, Zeng J, Kong B, Geng X, Li D, Gao X, Liang K, Xu L, Lian J, Huang S, Qiu J, Huang Y, Li H, RSC Adv., 7, 55513 (2017)
  40. Zhang Y, Zhao Y, Cao S, Yin Z, Cheng L, Wu L, ACS Appl. Mater. Interfaces, 7, 29982 (2017)
  41. Wang H, Liu Z, Chen X, Han P, Dong S, Cui G, J. Solid State Electrochem., 15, 1179 (2011)
  42. Katarzyna L, Agnieszka S, Ilona A, CHEMIK, 67, 1138 (2013)
  43. Kim C, Lee JW, Kim JH, Yang KS, Korean J. Chem. Eng., 23(4), 592 (2006)
  44. Subramanian V, Luo C, Stephan AM, Nahm KS, Thomas S, Wei B, J. Phys. Chem. C, 111, 7527 (2007)
  45. Wang Q, Cao Q, Wang XY, Jing B, Kuang H, Zhou L, J. Power Sources, 225, 101 (2013)
  46. Hu CC, Wang CC, Wu FC, Tseng RL, Electrochim. Acta, 52(7), 2498 (2007)
  47. Jisha MR, Hwang YJ, Shin JS, Nahm KS, Kumar TP, Karthikeyan K, Dhanikaivelu N, Kalpana D, Renganathan NG, Stephan AM, Mater. Chem. Phys., 115(1), 33 (2009)
  48. Gao K, Niu Q, Tang Q, Guo Y, Wang L, J. Electron. Mater., 47, 337 (2018)
  49. Liang Q, Ye L, Huang ZH, Xu Q, Bai Y, Kang F, Yang QH, Nanoscale, 6, 13831 (2014)
  50. Ma F, Wan J, Wu G, Zhao H, RSC Adv., 5, 44416 (2015)
  51. Li Z, Lv W, Zhang C, Li B, Kang F, Yang QH, Carbon, 92, 11 (2015)
  52. Qu WH, Xu YY, Lu AH, Zhang XQ, Li WC, Bioresour. Technol., 189, 285 (2015)
  53. Rufford TE, Hulicova-Jurcakova D, Fiset E, Zhu Z, Lu GQ, Electrochem. Commun., 11, 974 (2009)
  54. Cheng L, Guo P, Wang R, Ming L, Leng F, Li H, Zhao X, Colloids Surf. A: Physicochem. Eng. Asp., 446, 127 (2014)
  55. Gopalakrishnan A, Sahatiya P, Badhulika S, Mater. Lett., 198, 46 (2017)
  56. Chen M, Kang X, Wumaier T, Dou J, Gao B, Han Y, Xu G, Liu Z, Zhang L, J. Solid State Electrochem., 17, 1005 (2013)