화학공학소재연구정보센터
Journal of Polymer Science Part B: Polymer Physics, Vol.35, No.12, 1989-1991, 1997
Scaling Analysis of the Temperature-Dependence of Intrinsic-Viscosity
The scaling predictions for the temperature dependence of the intrinsic viscosity of flexible polymers are briefly reviewed. When the predictions are fit to a power law over a fixed range of chain length, a relation between the exponent and prefactor of the Mark-Houwink-Sakurada equation emerges. In comparing with the experimental data compilation of Rai and Rosen, we conclude that real polymer systems are nowhere near the true good solvent limit, even when the exponent matches the good solvent prediction.