Pd-Au/TiO2 bimetallic catalysts with varied Au contents were prepared by the sequential photocatalytic deposition method and the liquid phase catalytic hydrogenation reduction of bromate over these catalysts was investigated. The catalysts were characterized using X-ray diffraction, transmission electron microscope, UV-vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, H-2 chemisorption and energy dispersive spectroscopy. Characterization results showed that Pd atoms were site-deposited on the surface of varied size Au cores and formed Pd-on-Au core-shell like bimetallic nanoparticles on TiO2. The bimetallic catalysts showed higher Pd dispersions and more exposed active sites than that of Pd/TiO2, and the amount of exposed active sites first increased then decreased with Au content. For a similar Pd loading, the bimetallic catalyst exhibited volcano-shape activity as a function of Au loading and the highest activity was identified on Pd-Au(1.0)/TiO2 with Au core size around 8.4 nm. In addition, the catalytic reduction of bromate could be well-fitted by the Langmuir-Hinshelwood model, reflecting an adsorption controlled mechanism.